Semiconductor device having element isolation structure

Active solid-state devices (e.g. – transistors – solid-state diode – Integrated circuit structure with electrically isolated... – Including dielectric isolation means

Reexamination Certificate

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C257S506000, C257S513000, C257S524000

Reexamination Certificate

active

06635945

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention relates to a process for producing a semiconductor device having a highly reliable trench isolation structure and a semiconductor device produced thereby.
An STI (shallow trench isolation) structure [or an SGI (shallow groove isolation) structure] is now available to make an electrical isolation between adjacent elements such as transistors, etc. on a semiconductor substrate. As shown in
FIGS. 6A-6D
, the STI structure typically comprises a shallow trench formed on a silicon substrate
1
and an oxide film embedded in the trench; and is suitable for devices of up to 0.25 &mgr;m process technologies, because its processing dimensional precision is higher than that of the so-far-used LOCOS structure.
That is, a pad oxide film
2
is formed on the surface of a silicon substrate
1
by thermal oxidation, and an oxidation prevention film
3
is deposited on the pad oxide film
2
. Then, a shallow trench is formed in the silicon substrate
1
(FIGS.
6
A and
6
B). Then, an element-isolating, thermally oxidized film
5
is formed in the trench of the silicon substrate
1
(FIG.
6
C). Then, an isolation film
6
is formed thereon and filled in the trench (FIG.
6
D).
However, the trench of the STI structure is formed by anisotropic dry etching (FIG.
6
B), whereby corners A are formed at the upper trench edges. When further oxidized as such, the upper trench edges of the Si substrate are sometimes shaped into sharp corners
4
as shown in FIG.
6
C.
The presence of such sharp corners
4
at the upper trench edges in the substrate
1
gives rise to an electric field concentration or a stress concentration, sometimes resulting in abnormal electrical characteristics of transistors.
To solve such problems, for example, A. Chatterjee, et al propose a process for rounding the upper trench edges in a substrate to a desired curvature (Technical Digest of IEDM '96, pp. 829-832).
FIGS. 7A-7E
show the process for giving a curvature to the upper trench edges in the substrate.
A resist
13
, a TEOS film
15
and an oxidation prevention film
3
are patterned (FIG.
7
A), and a LOCOS film
12
is then formed by oxidation (FIG.
7
B). The LOCOS film
12
is then removed and an TEOS film
15
(an oxide film) is formed as a mask on the sides of the oxidation prevention film
3
(
FIG. 7C
) and a trench is formed (FIG.
7
D). Then, the trench is oxidized to give a curvature to the upper trench edges of STI (FIG.
7
E).
However, the process for giving a curvature to the upper trench edges in substrate requires two runs of oxidation (
FIGS. 7B and 7E
) and one run of film deposition (
FIG. 7C
) to obtain a substrate profile with a curvature at such upper trench edges, resulting in a complication of process steps.
BRIEF SUMMARY OF THE INVENTION
An object of the present invention is to provide a simplified process for producing a semiconductor device with round upper trench edges of a curvature and a semiconductor device produced thereby.
The present invention provides a process for producing a semiconductor device, which comprises:
(a) a step of forming a pad oxide film on the circuit-forming side of a semiconductor substrate,
(b) a step of forming an oxidation prevention film on the pad oxide film,
(c) a step of removing the oxidation prevention film and the pad oxide film at a desired position, thereby exposing the surface of the semiconductor substrate,
(d) a step of horizontally recessing the pad oxide film,
(e) a step of etching the exposed surface of the semiconductor substrate by isotropic etching,
(f) a step of forming a trench to a desired depth, using the oxidation prevention film as a mask,
(g) a step of horizontally recessing the pad oxide film,
(h) a step of oxidizing the trench formed in the semiconductor substrate,
(i) a step of embedding an embedding isolation film in the oxidized trench,
(j) a step of removing the embedding isolation film formed on the oxidation prevention film,
(k) a step of removing the oxidation prevention film formed on the circuit-forming side of the semiconductor substrate, and
(l) a step of removing the pad oxide film formed on the circuit-forming side of the semiconductor substrate.
The present invention also provides a semiconductor device produced according to the aforementioned process.


REFERENCES:
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patent: 4693781 (1987-09-01), Leung et al.
patent: 4729815 (1988-03-01), Leung
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patent: 4923821 (1990-05-01), Namose
patent: 4931409 (1990-06-01), Nakajima et al.
patent: 5258332 (1993-11-01), Horioka et al.
patent: 5358891 (1994-10-01), Tsang et al.
patent: 5536675 (1996-07-01), Bohr
patent: 5541425 (1996-07-01), Nishihara
patent: 5683075 (1997-11-01), Gaul et al.
patent: 5696402 (1997-12-01), Li
patent: 5858859 (1999-01-01), Miyashita et al.
patent: 0 459 397 (1991-12-01), None
patent: 0 660 391 (1995-06-01), None
patent: 7-176604 (1996-07-01), None
patent: WO98/12742 (1998-03-01), None
A. Chatterjee et al., A Shallow Trench Isolation using LOCOS Edge for Preventing Corner Effects for 0.25/0.18 um CMOS Technologies and Beyond, Technical Digest of IEDM, pp. 829-832.

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