Semiconductor device and method of manufacturing the same

Active solid-state devices (e.g. – transistors – solid-state diode – Integrated circuit structure with electrically isolated... – Including dielectric isolation means

Reexamination Certificate

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C257S344000, C257S408000, C257S513000

Reexamination Certificate

active

06373119

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the invention
The present invention relates to a semiconductor device and a method of manufacturing the same, more particularly to a semiconductor device comprising a trench element separation structure and a method of manufacturing the same.
2. Description of the Related Art
Hitherto, a LOCOS (Local Oxidation of Silicon) method has been used for forming an element separation region of a semiconductor device; however, for the purpose of producing a highly integrated semiconductor device, a method including a trench dug in a semiconductor substrate for filling an insulation film therein has also been used as a candidate method that replaces the LOCOS method, which needs a wide extent in the transverse direction. However, when the trench is buried with a material such as a silicon oxide film similar to an interlayer insulation film, it is necessary to ensure a sufficient margin, as described below, for mask alignment of a diffusion layer and a contact portion, and this has been an obstacle to improving the degree of integration.
A prior art in which a trench is dug in the semiconductor substrate to embed an insulation film therein (hereinafter this art will be referred to as a first prior art example) will be described with reference to FIG.
1
A and FIG.
1
B.
FIG. 1A
is a sectional view of an insulated gate field effect transistor (hereinafter referred to as a MOS transistor) having a trench element separation structure of the first prior art example.
As shown in
FIG. 1A
, element separation trench
102
for element separation use is formed in silicon substrate
101
, and then the trench is filled with a SiO
2
film according to a chemical vapor deposition (CVD) method to form filling insulation film
103
. Then in accordance with a manufacturing process of a normal MOS transistor, gate insulation film
104
, gate electrode
105
, source/drain region
106
,
106
a
and interlayer insulation film
107
comprising a SiO
2
made by a CVD method are formed on the silicon substrate.
Next, contact hole
108
for connecting the wiring is formed in source/drain region
106
a
, and contact plug
109
is filled in the contact hole
108
. Subsequently, wiring
110
laid on interlayer insulation film
107
and contact plug
109
are connected.
In case of forming this contact hole
108
, it is usual to provide a design margin X of a fixed value between contact hole
108
and element separation trench
102
giving consideration to mask alignment leeway between source/drain region
106
a
and contact hole
108
. If the margin X is insufficient and positional misalignment of the mask takes place, as shown in
FIG. 1B
, contact hole
108
a
is formed partially overlapping with element separation trench
102
. At the time when the contact hole is formed, etching time is usually set with a 30 to 100% margin over an expected normal time considering the influence of the dispersion of data such as the film thickness of interlayer insulation film
107
or the etching speed which is to be generated during a manufacturing process. If filling insulation film
103
filling element separation trench
102
and interlayer insulation film
107
are formed with the same material and the value of the margin X is insufficient, contact hole
108
a
formed by etching will dig filled insulation film
103
.
In such a state, contact plug
109
filled in contact hole
108
a
will come to be connected with silicon substrate
101
at an exposed side wall of element separation trench
102
. This contact plug
109
also connects with source/drain region
106
a
. Since silicon substrate
101
and source/drain region
106
a
are short-circuited as described above, the MOS transistor will fail to operate normally. A MOS transistor of
FIG. 1B
comprises gate insulation film
104
, gate electrode
105
and source/drain regions
106
,
106
a
in the same manner as that of FIG.
1
A.
An invention developed for overcoming this kind of drawback is disclosed in Japanese Patent Laid-open Gazette 190847/1987 (hereinafter this art is referred to as a second prior art example).
FIG. 2
is a sectional view of a MOS transistor having a trench element separation structure of the second prior art example.
On the surface of element separation trench
202
formed in silicon substrate
201
, there is formed silicon nitride film
203
of several tens of nm in thickness, and the remaining part inside the trench is filled with filling insulation film
204
. On the surface of silicon substrate
201
where no element separation structure is formed, gate insulation film
205
, gate electrode
206
and source/drain region
207
,
207
a
of the MOS transistor are formed, and interlayer insulation film
208
composed of an oxide film is formed thereon covering all the silicon substrate
201
.
In the manufacturing process of the second prior art example, when contact hole
209
for connecting wiring is formed in source/drain region
207
a
and then wiring
211
laid on the interlayer insulation film is connected with source/drain region
207
a
of the MOS transistor under the condition that the mask alignment margin between source/drain region
207
a
and contact hole
209
is insufficient, it is probable that the contact hole will be formed partially overlapping with the element separation region. However, even in such a case, a silicon substrate on the side wall of element separation trench
202
is protected by silicon nitride film
203
because the etching speed of silicon nitride film
203
is slow compared with that of a silicon oxide film which constitutes interlayer insulation film
208
. Consequently, there is no probability of a short circuit occurring between wiring
211
and silicon substrate
201
.
Certainly, the second prior art example can solve the technical problem of the first prior art example. However, there is another problem in the technique of the second prior art example in that, since silicon nitride film
203
is directly deposited on the surface of a silicon substrate inside element separation trench
202
formed in silicon substrate
201
, a crystal defect is generated in an area near the silicon substrate surface facing element separation trench
202
which is caused by thermal changes produced in the following processes, thereby causing an increase in the leak current which flows from a diffusion layer that constitutes source/drain region
207
a
to silicon substrate
201
.
This is because the elastic strength of silicon nitride film
203
is remarkably large compared with that of the silicon oxide film, and hence when thermal changes are applied to silicon nitride film
203
after being deposited on the silicon substrate, thermal stress is produced within the silicon, thereby causing crystal defects.
Leak current of this kind carried from the diffusion layer to the silicon substrate functions not only to increase dissipation power during the operation waiting time of the semiconductor device, but to induce a latch-up phenomenon in the semiconductor device of a CMOS structure, thereby becoming a large cause of deteriorating the reliability of the product.
SUMMARY OF THE INVENTION
An object of the present invention is to provide a semiconductor device having a trench element separation structure and adapted to a high degree of integration while solving the technical problems of the prior art without having crystal defects produced in the silicon substrate, and a method of manufacturing the same.
Therefore, the semiconductor device of the present invention has a trench element separation region in a fixed region of the semiconductor substrate, the inside wall of the trench is covered with a first insulation film, and a second insulation film and a third insulation film are stacked in layers in this order and filled on the first insulation film in the trench.
Here, the third insulation film is formed so that the surface thereof may be positioned lower than the surface of the semiconductor substrate.
Further, an interlayer insulation film is formed so that it may cover the third

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