Self-emulsifiable polyisocyanate mixture and aqueous coating or

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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2521822, 25218222, 528 65, 528 67, 528 73, 528905, 524501, 524507, 524591, 525127, 525460, C08G 1810

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active

056313411

ABSTRACT:
A self-emulsifiable polyisocyanate mixture having a hexamethylene diisocyanate monomer content of not more than 1.0% by weight and an average NCO functionality of 2.0 to 3.7 obtained by subjecting hexamethylene diisocyanate to urethanation with a branched dihydric alcohol having overall 4 to 35 carbon atoms, of which 2 to 33 carbon atoms are a total number of the carbon atoms possessed by one or more branches, a hydrophilic surfactant having one or more active hydrogen atoms capable of reacting with NCO group and 3 to 90 alkylene oxide units, an aliphatic compound having one or more active hydrogen atoms capable of reacting with NCO group and 8 or more carbon atoms and an unbranched glycol having 1 to 10 carbon atoms; uretdione-forming reaction; and isocyanurate-forming reaction. Said self-emulsifiable polyisocyanate mixture is excellent in compatibility, dispersion stability and NCO group-stability and can be combined with water or a water-soluble resin and/or an aqueous emulsion, and if necessary, an additive to provide an aqueous coating or adhesive composition excellent in heat resistance, workability, coating film appearance, weather resistance and adhesion to substrate.

REFERENCES:
patent: 4663377 (1987-05-01), Hombach et al.
patent: 5200489 (1993-04-01), Jacobs et al.
patent: 5252696 (1993-10-01), Lass et al.
patent: 5373050 (1994-12-01), Morikawa et al.
patent: 5502149 (1996-03-01), Yoshida et al.

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