Selective thermal oxidation of hydrocarbons in zeolites by oxyge

Details Selective thermal oxidation of hydrocarbons in zeolites by oxyge Selective thermal oxidation of hydrocarbons in zeolites by oxyge

1999-06-17

2000-11-21

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568571, 568577, 20415715, 20415793, 210748, C07C 4504, C07B 3300

Patent

active

061505625

ABSTRACT:
A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

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Sheldon, Metalloporphyrins in Catalytic Oxidations, Ed. Marcel Dekker, New York, 1994.
Yoon et al, Electron- and Charge- Transfer Reactions with Zeolites, Chem.Rev., 93, 321-339, 1993.
Hai Sun, et al, Selective Oxidation of Toluene to Benzaldehyde by Oxygen with Visible light in Barium (2+) and Calcium (2+)--Exchanged Zeolite Y, J.Am.Chem.Soc., 116, 7951-7952, 1994.

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