Selective recovery of a nitrophenolic by-product from nitration

Liquid purification or separation – Processes – Making an insoluble substance or accreting suspended...

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210909, C02F 126

Patent

active

049869205

ABSTRACT:
A process of selectively recovering a nitrophenolic by-product, namely 2,4-dinitrophenol and picric acid, from nitration waste water in substantially pure form through the control of the solution pH of the nitration waste water and subsequent precipitation is provided. By adjusting the solution pH of the nitration waste water with an acid to a pH in the range of from about 4.0 to 0.5, the solubility of the selected nitrophenolic by-products is affected and the crystal formation of the individual by-products controlled.

REFERENCES:
patent: 4597875 (1986-07-01), Carr et al.

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