Selective reactions of free radicals with olefins in the presenc

Details Selective reactions of free radicals with olefins in the presenc Selective reactions of free radicals with olefins in the presenc

1973-09-24

1977-03-08

Jiles, Henry R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603461R, 2603462R, 2603473, 2603475, 2603478, 260456R, 2604653, 260483, 260484A, 260486R, 260497R, 260586C, 260595, 260597R, 260607AL, 260609B, 260644, C07D32704, C07C 6952, C07C 4502

Patent

active

040112390

ABSTRACT:
An olefin is reacted with a source of X free radical in the presence of an ion of manganese, vanadium, or cerium having a valence higher than the lowest valence above the zero valent form of the metal to form derivatives of the olefin that contain one or more functional groups. The free radical X is one that is resistant to substantial oxidation by the ion of the metal and is obtained from ketones, aldehydes, esters, nitriles, nitroparaffins, sulfoxides, thiosulfonic acid esters, alkanesulfonic acids, alkanesulfinic acids, and thiols.

REFERENCES:
Heiba, et al., JACS vol. 90:4, Feb. 14, 1968, p. 1082-1084.
Van Helden et al., Chem. Abstr. vol. 55, (1961), 17564i-17565b.

Affiliated with

Also associated with

Rating

Selective reactions of free radicals with olefins in the presenc does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Selective reactions of free radicals with olefins in the presenc, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective reactions of free radicals with olefins in the presenc will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1405929