Selective production of para-xylene

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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C07C 268

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active

042503450

ABSTRACT:
Process for the selective production of para-xylene by methylation of toluene in the presence of a catalyst comprising a crystalline aluminosilicate zeolite, said zeolite having a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12, which catalyst has undergone prior modification by the addition thereto of phosphorus oxide and magnesium oxide, each in an amount of at least about 0.25 percent by weight.

REFERENCES:
patent: 3965208 (1976-06-01), Butter et al.
patent: 4086287 (1978-04-01), Kaeding et al.

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