Selective production of ethyl mercaptan

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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C07C31904

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active

053528387

ABSTRACT:
A process for selectively producing ethyl mercaptan from a reactant mixture such as, for example, refinery fuel gas mixture is provided which comprises contacting, in the presence of a catalyst such as, for example, oxides of cobalt and molybdenum supported on aluminum, the reactant mixture with hydrogen sulfide wherein the reactant mixture contains ethylene and at least one other olefin such as, for example, propylene. The reactant mixture can also contain other components such as, for example, hydrogen, ethane, methane, propylene, or propane, or mixtures thereof.

REFERENCES:
patent: 3994980 (1976-11-01), Kubicek
Reid, Organic Chemistry of Bivalent Sulfur, vol. I, pp. 20-21, 1980.
Reid, Organic Chemistry of Bivalent Sulfur, vol. I, pp. 18-19, 1958.
Allison et al (ACS Div. Petrol. Chem. Ann. Mtg. Atlantic Cit, Sep. 8-13, 1968, vol. 13, pp. 207-209).

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