Selective production of 2,6-dimethylnaphthalene

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By alkyl or aryl transfer between molecules – e.g.,...

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585472, 585474, C07C 1512

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active

056707045

ABSTRACT:
A method for the highly selective production of 2,6-dimethlynaphthalene by the transmethylation of naphthalene or 2-methylnaphthalene by the use of a specific acid catalyst and a highly regeospecific methylating agent.

REFERENCES:
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patent: 4950824 (1990-08-01), Shiroto et al.
Olah et al., "Alkylation of Naphthalene with Alkyl Halides"; J. Am. Chem. Soc., 98:7, pp. 1839-1842; Mar. 1976.
Shimada et al; "Ethylation and Transethylation of Naphthalene"; Bulletin of the Chem. Soc. of Japan; vol. 48(II); pp. 3306-3308; Nov., 1975.

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