Selective preparation of trans-perhydroacenaphthene

Details Selective preparation of trans-perhydroacenaphthene Selective preparation of trans-perhydroacenaphthene

1987-05-04

1988-08-02

Davis, Curtis R.

Chemistry of hydrocarbon compounds

Adding hydrogen to unsaturated bond of hydrocarbon, i.e.,...

Hydrocarbon is aromatic

585270, C07C 503

Patent

active

047615109

ABSTRACT:
Trans-isomers of perhydroacenaphthene are selectively prepared through hydrogenation of acenaphthene by effecting hydrogenation at 200.degree. to 300.degree. C. in the presence of a nickel catalyst on a kieselguhr carrier.

REFERENCES:
patent: 3128316 (1964-04-01), Schneider
patent: 3859370 (1975-01-01), Carter et al.
patent: 3997617 (1976-12-01), Hosler et al.
patent: 4041086 (1977-08-01), Moore et al.
"Preparation of Diamondoid Hydrocarbons by Rearrangement Employing a Chlorinated Platinum-Alumina Catalyst", Journal of the American Chemical Society, by D. E. Johnston et al., Jun. 2, 1971, pp. 2798 and 2799.

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