Selective preparation of 1,2-dichloroethane

Details Selective preparation of 1,2-dichloroethane Selective preparation of 1,2-dichloroethane

1973-12-21

1976-07-06

Gantz, Delbert E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C 1702

Patent

active

039681793

ABSTRACT:
A process for the continuous chlorination of ethylene in the liquid phase in the absence of light and in the presence of 1,2-dichloroethane and dissolved ferric chloride wherein the reaction is carried out in a homogeneous reaction zone in which the reaction medium contains dissolved chlorine in an amount within the range of 1 to 20 g per kg of liquid reaction mixture and in which the ratio R between the molar hourly flow rate of ethylene introduced to the homogeneous reaction zone and the molar hourly flow rate of ethylene which saturates the 1,2-dichloroethane contained in the reaction zone is within the range of 0 to 140.

REFERENCES:
patent: 1231123 (1917-06-01), Brooks et al.
patent: 2393367 (1946-01-01), Hammond
patent: 2765353 (1956-10-01), Neher
patent: 3267163 (1966-08-01), Tsutsumi et al.
patent: 3475504 (1969-10-01), Kircher et al.
patent: 3839475 (1974-10-01), Kurtz et al.

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