Selective oxoamination process

Details Selective oxoamination process Selective oxoamination process

1980-12-16

1981-11-10

Doll, John

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564473, 568423, 568454, C07C 8508, C07C 4550

Patent

active

042999855

ABSTRACT:
This invention concerns the synthesis of linear alkyl primary amines from a-olefins via an oxoamination process comprising (a) hydrogen and carbon monoxide addition to olefinic substrates to obtain aldehyde-containing compounds in the presence of ligand-stabilized platinum(II) halide catalysts with Group IVB metal halide cocatalysts, and (b) reductive amination of said aldehydic intermediates in the presence of oxide-supported, nickel catalysts.

REFERENCES:
patent: 3067255 (1962-12-01), Scholz et al.
patent: 3520933 (1970-07-01), Adam et al.
patent: 3981925 (1976-09-01), Schwager et al.
patent: 4036883 (1977-07-01), Voges et al.

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