Selective oxidative conversion of methane to methanol,...

Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction

Reexamination Certificate

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C518S713000, C518S714000

Reexamination Certificate

active

07846978

ABSTRACT:
The present invention relates to a method of producing methanol from a methane source by oxidizing methane under conditions sufficient to a mixture of methanol and formaldehyde while minimizing the formation of formic acid and carbon dioxide. The oxidation step is followed by treatment step in which formaldehyde is converted into methanol and formic acid which itself can further be converted into methanol via catalytic hydrogenation of intermediately formed methyl formate.

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Barbero et al., “Breakthrough in the direct conversion of methane into c1-oxygenates,” Chem. Commun., 1184-1185 (2001).
Larkin et al., “The direct partial oxidation of methane to organic oxygenates using a dielectric barrier discharge reactor as a catalytic reactor analog,” Catalysis Today 71: 199-210 (2001).
Zang et al., “Comparative studies on direct conversion of methane to methanol/formaldehyde over La—Co—O and ZrO2supported molybdenum oxide catalysts,” Topics in Catalysis 32(3-4): 215-223 (2005).
International Search Report, Application No. PCT/US2006/013743, Aug. 4, 2006.

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