Selective oxidation of hydrogen sulfide in the presence of bismu

Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur

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4235768, 423230, 4232441, B01D 5352

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active

055975461

ABSTRACT:
The present invention discloses a method of selectively oxidizing hydrogen sulfide to elemental sulfur, in which a H.sub.2 S-containing gas mixture contacts with an oxygen-containing gas at 50.degree.-500.degree. C. in the presence of a bismuth-based catalyst. The reaction product mixture contains substantially no sulfur dioxide. The bismuth-based catalyst may further contain molybdenum or vanadium atom.

REFERENCES:
patent: 4212852 (1980-07-01), Aibe et al.
patent: 4444908 (1984-04-01), Hass et al.
J. A. Lagas and J. Borsboom, "Selective-oxidation catalyst improves Claus process", Oil and Gas Journal, 86(41), pp. 68-71, (Oct. 10, 1988).
P. F. M. T. van Nisselrooy and J. A. Lagas, "SuperClaus reduces SO.sub.2 emission by the use of a new selective oxidation catalyst", Catalysis Today, 16, pp. 263-271, 1993. (No month).

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