Selective oxidation of chrysanthemyl alcohol

Details Selective oxidation of chrysanthemyl alcohol Selective oxidation of chrysanthemyl alcohol

1975-09-24

1977-09-20

Helfin, Bernard

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260598, C07C 5126, C07C 4500

Patent

active

040497062

ABSTRACT:
Chrysanthemyl alcohol is selectively oxidized to the corresponding aldehyde by contact with oxygen-containing gas in the presence of supported noble metal catalyst composed of platinum on carbon. The obtained aldehyde may be further converted to chrysanthemic acid by oxidation with a solid inorganic oxidizing agent such as silver oxide in excess of stoichiometric quantity, or by reaction with a catalytic amount of oxidation promoting catalyst such as silver oxide in the presence of cupric oxide and molecular oxygen.

REFERENCES:
patent: 3778477 (1973-12-01), Mueller et al.
patent: 3840566 (1974-10-01), Lalancette
patent: 3926860 (1975-12-01), Chappell
Dauben et al., Jour. Org. Chem., vol. 34 (1969), 2301-2306.
Crombie et al., Jour. Chem. Soc. (1963) 4983.
Mills et al., Jour. Chem. Soc., (Perkin I) (1973) 133-137.
Heyns et al., Newer Methods of Preparative Organic Chemistry, vol. 2 (1963) 304-311, 320-323, 328-329, 332-335.

Affiliated with

Also associated with

Rating

Selective oxidation of chrysanthemyl alcohol does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Selective oxidation of chrysanthemyl alcohol, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective oxidation of chrysanthemyl alcohol will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-670969