Selective hydroperoxidation of polyolefins in an aqueous slurry

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 58, 526351, C08F11006, C08F 806

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active

RE0291005

ABSTRACT:
Polyolefins are selectively hydroperoxidized in an aqueous slurry with an ozone-oxygen mixture at temperatures between 65.degree. and 100.degree. C for a time which does not exceed one hour to introduce sufficient hydroperoxides for later graft copolymerization while minimizing formations of higher oxidation products of the polymer and limiting molecular weight degradation.

REFERENCES:
patent: 2911398 (1959-11-01), Vandenberg
patent: 3069382 (1962-12-01), Nikolov et al.
patent: 3284541 (1966-11-01), Stanton et al.
patent: 3322711 (1967-05-01), Bush et al.
patent: 3458597 (1969-07-01), Jabloner

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