Selective hydrogenation of unsaturated compounds

Details Selective hydrogenation of unsaturated compounds Selective hydrogenation of unsaturated compounds

1976-06-30

1977-04-26

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431N, 260439CY, 260593R, C07B 100, C07C 4500

Patent

active

040201082

ABSTRACT:
In a process for the catalytic hydrogenation of unsaturated compounds, which process is characterizable as employing for the active catalyst a glyoxime complexed with cobalt and a base, referred to as a cobaloxime catalyst, the improvement for obtaining increased conversion and/or yield comprising employing a large excess of the glyoxime complexing agent in the hydrogenation reaction. The invention is particularly applicable to the selective reduction of certain .alpha.,.beta.-unsaturated aliphatic ketones and is described with reference to the highly selective hydrogenation of carvone to dihydrocarvone.

REFERENCES:
patent: 3110747 (1963-11-01), Mulleneaux
patent: 3130237 (1964-04-01), Wald
patent: 3463810 (1969-08-01), Malhotra et al.
Beilstein, Handbook der Org. Chem., vol. VII, III supp., pp. 336-337.
Armstrong et al., Chem. Abst., vol. 19, pp. 3054-3055, (1925).
Ohgo et al., Bull. Chem. Soc., Jap., vol. 44, pp. 283-285, (1971).
Schrauzer et al., Ber., vol. 99, pp. 602-610, (1965).

Affiliated with

Also associated with

Rating

Selective hydrogenation of unsaturated compounds does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Selective hydrogenation of unsaturated compounds, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective hydrogenation of unsaturated compounds will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2087216