Selective hydrogenation of conjugation diolefin polymers with ra

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253328, 5253329, 5253331, 5253332, 525339, C08F 804

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051771551

ABSTRACT:
This invention provides a catalyst and a process for the hydrogenation of conjugated diolefin polymers which first involves the polymerization or copolymerization of such monomers with an organo alkali metal polymerization initiator in a suitable solvent thereby creating a living polymer. The living polymer can be terminated by the addition of hydrogen. Finally, selective hydrogenation of the unsaturable double bonds in the conjugated diolefin units of the terminated polymer is carried out in the presence of an initiator and at least one rare earth compound of the formula

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