Selective hydrogenation catalyst designed for raw gas feed...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making

Reexamination Certificate

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C502S304000, C502S327000, C502S328000, C502S329000, C502S330000, C502S332000, C502S333000, C502S339000, C502S347000, C502S348000, C502S349000, C502S350000, C502S351000, C502S355000, C502S439000

Reexamination Certificate

active

07745370

ABSTRACT:
A catalyst for selective hydrogenation of acetylenes and diolefins, particularly in a raw gas feed stream for front end selective hydrogenation. The catalyst contains a low surface area carrier with a surface area from about 2-20 m2/g, wherein the pore volume of the pores of the carrier is greater than about 0.4 cc/g, at least 90 percent of the pore volume of the pores is contained within pores having a pore diameter greater than about 500 Å and about 1 to about 2 percent of the total pore volume is contained in pores with a pore diameter from about 500 to about 1,000 Å. The palladium comprises about 0.01 to about 0.1 weight % and a Group IB metal comprises about 0.005 to about 0.06 weight % of the catalyst.

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