Selective extraction of molybdenum and vanadium from spent catal

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group vib metal

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423 53, 423 62, 423 66, 423 68, 423127, 423131, 423140, 423147, 423150, 75101R, 75108, 75119, 75121, 502 25, C01G 3100, C01G 3900

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046666850

ABSTRACT:
Spent hydrodesulfurization catalysts containing alumina, at least one metal from the group consisting of molybdenum, tungsten and vanadium and at least one metal from the group consisting of nickel and cobalt, sulfur, and, usually, residual oil are oxygen pressure leached at a temperature of at least about 400.degree. F. with a base from the group consisting of sodium hydroxide and sodium aluminte in at least stoichimetric amount to yield a solution having a pH between about 7 and 9 containing dissolved molybdenum, vanadium and any tungsten which may be recovered and a readily filterable residue containing aluminum, nickel and cobalt which may be worked up to recover the valuable constituents, with overall processing being accomplished in an environmentally acceptable manner.

REFERENCES:
patent: 1709284 (1929-04-01), Sauer
patent: 2208616 (1940-07-01), Wellman et al.
patent: 3824193 (1974-07-01), Williams et al.
patent: 4145397 (1979-03-01), Toida et al.
patent: 4401631 (1983-08-01), Canavesi et al.
patent: 4495157 (1985-01-01), Sebenik et al.

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