Selective conversion of d-isolimonene to d-3-menthene

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Partial

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585355, 585947, C07C 1320, C07C 505, C07C 513, B01J 2344

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042490286

ABSTRACT:
d-3-Menthene of high optical purity is obtained by the selective isomerization/hydrogenation of d-isolimonene in the presence of minor amounts of a palladium catalyst at temperatures up to 200.degree. C. and pressures of preferably about 100-500 psig.

REFERENCES:
patent: 3407241 (1968-10-01), Booth
patent: 3804914 (1974-04-01), Fahey
patent: 3925494 (1975-05-01), Fahey
patent: 4190612 (1980-02-01), Masilamani et al.

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