Selective conversion of benzene to tercyclohexane

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Hydrocarbon is aromatic

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585268, 585350, 585360, 585375, C07C 510, C07C 1300

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active

054498473

ABSTRACT:
There is provided a process for preparing tercyclohexane by reacting benzene with hydrogen. The process involves the use of a catalyst comprising an acidic solid and a hydrogenation component. The acidic solid may comprise a Group IVB metal oxide, such as zirconia, modified with an oxyanion of a Group VIB metal, such as tungsten. The hydrogenation component may comprise platinum.

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Hino, M. et al., "Synthesis of Solid Superacid of Tungsten Oxide supported on Zirconia and its Catalytic Action for Reactions of Butane and Pentane," J. Chem. Soc. Chem. Comm., 1259-1260 (1988).
Arata, K. et al., "Synthesis of Solid Superacid of Tungsten Oxide Supported on Zirconia and Its Catalytic Action," Proceedings 9th International Congress on Catalysis, 4, 1727-1735 (1988).

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