Selective alkylation of aromatic hydrocarbons using a mixed ethy

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585468, 585809, 585830, 585868, C07C 352

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active

043872590

ABSTRACT:
Aromatic hydrocarbons are selectively alkylated using an alkylating mixture containing both ethylene and propylene. By employing a zeolite ZSM-12 based alkylation catalyst, essentially only the propylene from the olefin-containing alkylation mixture will react with the aromatic hydrocarbon to thereby form both an alkylaromatic product enriched in propylated alkylaromatic and a propylene-free residual olefin-containing mixture enriched in the unreacted ethylene.

REFERENCES:
patent: 3086998 (1963-04-01), Hervert
patent: 3755483 (1973-08-01), Burress
patent: 4049737 (1977-09-01), Dwyer et al.
patent: 4291185 (1981-09-01), Kaeding
Chem. Abstracts, vol. 55, No. 17548b.
Chem. Abstracts, vol. 76, No. 13942c.
Chem. Abst., vol. 55, No. 17548b.
Chem. Abst., vol. 76, No. 13942c.

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