Secondary lithium battery

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

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429218, H01M 616

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active

047374241

ABSTRACT:
The present invention provides an electrolyte for use on a secondary lithium battery comprising amorphous V.sub.2 O.sub.5 base cathode active material, a metallic lithium base active material, and an electrolytic solution lithium salt dissolved in a mixed organic solvent. The organic solvent is ethylene carbonate mixed with one organic solvent of 2-methyltetrahydrofuran, 2,5-dimethyltetrahydrofuran, 1,3-dioxalan, 4-methyl-1,3-dioxalan, 1,2-dimethoxyethane, etc. The mixed ratio of ethylene carbonate ranges within 10 to 50%, and water content of the electrolytic solution ranges within 400 to 5 ppm, and the content of impurities other than water ranges within 1000 to 10 ppm. The resultant secondary lithium battery is excellent in charge-discharge cycle life.

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Electrochimica Acta, vol. 29, No. 10, pp. 1471-1476 (1984), Ethylene Carbonate/Ether Mixed Solvents Electrolyte for Lithium Batteries, S.-I. Tobishima et al.
Electrochimica Acta, vol. 30, No. 12, pp. 1715-1722 (1985), Lithium Cycling Efficiency and Conductivity for High Dielectric Solvent/Low Viscosity Solvent Mixed Systems, Shin-ichi Tobishima et al.
Electrochimica Acta, vol. 29, No. 2, pp. 267-271 (1984), Ethylene Carbonatepropylene Carbonate Mixed Electrolytes for Lithium Batteries, Shin-ichi Tobishima et al.

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