Second cycle asymmetric dihydroxylation reaction

Details Second cycle asymmetric dihydroxylation reaction Second cycle asymmetric dihydroxylation reaction

2005-02-08

2005-02-08

Shippen, Michael L. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C560S060000, C568S811000, C568S860000

Reexamination Certificate

active

06852874

ABSTRACT:
A process for catalyzing asymmetric dihydroxylations of olefins employs an Os(VI) complex as a catalytic intermediate in the formation of chiral vicinal diol products. The process requires a chiral bidentate ligand that favors diol formation in the “second cycle” of asymmetric dihydroxylation.

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