Sealant with siloxaphobic surface, composition, and method to pr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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556428, 556422, 556470, 528 34, C08G 7724

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active

053570251

ABSTRACT:
A sealant made from a room temperature curing polydimethylsiloxane composition has a siloxaphobic surface layer at the air-sealant interface where this layer is a fluorocarbon compound and a drying oil oxidation product. Elastomeric compositions made from polydimethylsiloxanes having both low reactivity endgroups and high reactivity endgroups and a siloxaphobic agent of fluorocarbon alcohol or a reaction product of the fluorocarbon alcohol and a hydrolyzable silane, are particularly useful for sealing buildings because they can withstand the expansions and contractions. One siloxaphobic agent is the reaction product between a fluorocarbon alcohol and a methyltri(methylethylketoximo)silane and the formula of one of the reaction product compounds is ##STR1## wherein x has an average value of at least 6.

REFERENCES:
patent: 2993925 (1961-07-01), Husted
patent: 3828087 (1974-08-01), Pittman
patent: 4460740 (1984-07-01), Arai
patent: 4683251 (1987-07-01), Mikami
patent: 4695603 (1987-09-01), Inoue et al.
patent: 5126420 (1992-06-01), Satoh et al.
patent: 5235017 (1993-08-01), O'Lenick, Jr.
Noll, Chemistry and Technology of Silicones, 1968, pp. 142-147.

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