Wells – Processes – Material placed in pores of formation to treat resident...
Reexamination Certificate
2007-09-18
2007-09-18
Suchfield, George (Department: 3676)
Wells
Processes
Material placed in pores of formation to treat resident...
C166S307000, C166S308200, C166S310000, C166S312000, C507S222000, C507S224000, C507S225000, C507S927000
Reexamination Certificate
active
11649492
ABSTRACT:
A formulation containing a copolymer derived from a cationic monomer effectively inhibits and controls the formation of inorganic scales. The formulation has particular application in the removal of zinc sulfide and iron sulfide scales formed when zinc bromide brines are used as completion fluids. The copolymer exhibit high solubility in high-density brines, such as zinc bromide brines. The polymers may be introduced into an oil or gas well as a portion of a carrier fluid or with brine. The preferred copolymer for use in the invention contains an acrylamide unit and a diallyldimethylammonium salt and, optionally, an acrylic acid or a salt thereof. The weight average molecular weight of such inhibitor copolymers is generally between from about 500,000 to about 5,000,000.
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Graham, G.M., et al., “The Impact of Dissolved Iron . . . ” Presented at the SPE International Symposium on Oilfield Chemistry, Houston, TX, Feb. 5-7, 2003 (SPE 80254).
Graham, G.M., et al., “The Importance of Appropriate Laboratory Procedures . . . ” Presented at the SPE Oilfield Scale Symposium, Aberdeen, U.K., Jan. 30-31, 2002 (SPE 74679).
Graham, G.M., et al., “Occurance, Prediction and Prevention of Zinc Sulfide Scale . . . ” Presented at the SPE Third International Symposium on Oilfield Scale, Aberdeen, U.K., Jan. 30-31, 2001 (SPE 68317).
Ke Mingjie
Qu Qi
BJ Services Company
Jones John Wilson
Jones & Smith, LLP
Suchfield George
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