Sampling of hydrocarbons from geological formations

Earth boring – well treating – and oil field chemistry – Earth boring – Contains organic component

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C507S203000, C507S101000, C507S201000, C507S116000, C507S218000

Reexamination Certificate

active

07094736

ABSTRACT:
A method of separating from a mixture of oil-based drilling fluid and sample of formation hydrocarbon, the liquid component of the drilling fluid, which method comprises treating, e.g. chemically, the mixture in a way that selectively substantially affects the liquid component of the drilling fluid, producing one or more treatment products, while leaving the formation hydrocarbon substantially unaffected; and separating the treatment products from the formation hydrocarbon, by solvent extraction. The liquid component of the drilling fluid conveniently comprises one or more esters (which do not occur in significant quantities in naturally occuring formation hydrocarbons) and which can be hydrolysed to give water-soluble products readily removable from the formation hydrocarbon. The invention is applicable to sampling of formation hydrocarbon using wireline formation testers or sampling tools.

REFERENCES:
patent: 3369345 (1968-02-01), Moore et al.
patent: 4174629 (1979-11-01), Striegler
patent: 4936139 (1990-06-01), Zimmerman et al.
patent: 5165477 (1992-11-01), Shell et al.
patent: 5232910 (1993-08-01), Mueller et al.
patent: 5252554 (1993-10-01), Mueller et al.
patent: 5725771 (1998-03-01), Aliphat et al.
patent: 5881813 (1999-03-01), Brannon et al.
patent: 6232274 (2001-05-01), Hughes et al.
patent: 2 324 322 (1998-10-01), None
patent: 2 332 223 (2000-01-01), None
patent: 92/15771 (1992-09-01), None
Akram et al A model to predict wireline formation tester sample contamination SPE Reservoir Evaluation & Engineering, vol. 2, No. 6, 1999, pp. 499-505.
Almond et al Utilization of biologically generated acid for drilling fluid damage removal and uniform acid placement across long formation intervals European Formation Damage Conference, The Hague, May 15-16, 1995, SPE 30123.
Anderson et al The hydrolysis of p-nitrophenyl acetate: a versatile reaction to study enzyme kinetics Journal of Chemical Education, vol. 71, No. 8, 1994, pp. 715-718.
Atanasov et al Environmental biosensors based on mediatorless bioelectrocatalysis 217thACS National Meeting, Anaheim, CA, Mar. 21-25, 1999, pp. 486-487.
Badry et al New wireline formation tester techniques and applications SPWLA 34thAnnual Logging Symposium, Calgary, Jun. 1993, paper zz.
Brown et al Synthetic base fluids Chemistry and Technology of Lubricants (Mortier and Orszulik eds.), second edition, Blackie Academic & Professional, London 1997, pp. 34-41.
Carlson et al Meeting the challenges of deepwater Gulf of Mexico drilling with non-petroleum ester-based drilling fluids SPE International Petroleum Conference, Veracruz, Mexico, Oct. 10-13, 1994, SPE 28739.
Churan et al Onsite and offsite monitoring of synthetic-based drilling fluids for oil contamination SPE/EPA Exploration and Production Environmental Conference, Dallas, Mar. 3-5, 1997, SPE 37906.
Curiale et al Occurrence and origin of olefins in crude oils. A critical review. Organic Geochemistry, vol. 29, No. 1, 1998, pp. 397-408.
Felling et al Characterization of in-situ fluid responses using optical fluid analysis SPE Annual Technical Conference and Exhibition, San Antonio, Oct. 5-8, 1997, SPE 38649.
Fernandez-Lafuente et al Immobilization of lipases by selective adsorption on hydrophobic supports Chemistry and Physics of Lipids, vol. 93, 1998, pp. 185-197.
Friedheim et al Second generation synthetic fluids in the North Sea: are they better? IADC/SPE Drilling Conference, New Orleans, Mar. 12-15, 1996, SPE 35061.
Friedheim et al Superior performance with mineral environmental impact: a novel nonaqueous drilling fliud IADC/SPE Drilling Conference, Amsterdam Feb. 23-25, 1993, SPE 25753.
Furniss et al Practical organic chemistry Vogel's Textbook of Practical Organic Chemistry, 5thedition, Longman Scientific and Technical, 1989, p. 158.
Hammond One- and two-phase flow during fluid sampling by a wireline tool Transport in Porous Media, vol. 6, 1991, pp. 299-330.
Hanssen et al New enzyme process for downhole cleanup of reservoir drilling fluid filtercake SPE International Symposium on Oilfield Chemistry, Houston, Feb. 16-19, 1999, SPE 50709.
Harris et al New applications for enzymes in oil and gas production SPE European Petroleum Conference, The Hague, Oct. 20-22, 1998, SPE 50621.
Hashem et al Determination of producible hydrocarbon type and oil quality in wells drilled with synthetic oil-based muds SPE Reservoir Evaluation & Engineering, 2(2), 1999, pp. 125-133.
Heiss et al Polyethylene glycol monomethyl ether-modified pig liver esterase: preparation, characterization and catalysis of enantioselective hydrolysis in water and acylation in organic solvents Tetrahedron Letters, vol. 36, No. 22, 1995, pp. 3833-3836.
Jacques et al A comparison of field drilling experience with low-viscosity mineral oil and diesel muds IADC/SPE Drilling Conference, New Orleans Feb. 18-21, 1992, SPE 23881.
Kenny Ester-based muds show promise for replacing some oil-based muds Oil & Gas Journal, vol. 91, No. 45, 1993, pp. 88-91.
Kinnear et al Direct electron transfer toEscherichia colifumarate reductase in self-assembled alkanethiol monolayers on gold electrodes Langmuir, 9, 1993, pp. 2255-2257.
Larter et al Reservoir geochemistry: methods, applications and opportunities The Geochemistry of Reservoirs (J.M. Cubitt and W.A. England eds.), Geological Society Special Publication No. 86, The Geological Society, London 1995, pp. 5-32.
Mar. Aliphatic nucleophilic substitution Advanced Organic Chemistry, 4thedition, Wiley-Interscience, New York, 1992, pp. 336-340.
Morris et al Using optical fluid analysis to evaluate downhole fluid sample contamination SPE European Petroleum Conference, The Hague, Oct. 20-22, 1998, SPE 50603.
Munro et al Biodegradation of base fluids used in synthetic drilling muds in a solid-phase test SPE/UKOOA European Environmental Conference, Aberdeen Apr. 15-16, 1997, SPE 37861.
Nicolle et al Geochemistry: a powerful tool for reservoir monitoring Middle East Oil Show, Bahrain, Mar. 15-18, 1997, SPE 37804.
Proett et al New wireline formation testing tool with advanced sampling technology SPE Annual Technical Conference, Houston, Oct. 3-6, 1999, SPE 56711.
Rissom et al Asymmetric reduction of acetophenone in membrane reactors: comparison of oxazaborolidine and alcohol dehydrogenase catalysed processes Tetrahedron: Asymmetry, 10, 1999, pp. 923-928.
Schlumberger Sampling Wireline formation testing and sampling, Houston, Texas, 1996, pp. 10-1 to 10-25.
Shubkin Polyalphaolefins Synthetic Lubricants and High-Performance Functional Fluids (Shubkin ed.), Marcel Dekker, Inc., New York, 1992, pp. 1-7.
Smits et al In-situ optical fluid analysis as an aid to wireline formation sampling SPE Formation Evaluation, 10, Jun. 1995, pp. 91-98.
Sousa et al Asymmetric hydrolysis of a meso-diester using pig liver esterase immobilised in hollow fibre ultrafiltration membrane Tetrahedron: Asymmetry 11, 2000, pp. 929-934.
Underhill et al Model-based sticking risk assessment for wireline formation testing tools in the US Gulf Coast SPE Annual Technical Conference, New Orleans Sep. 27-30, 1998, SPE 48963.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Sampling of hydrocarbons from geological formations does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Sampling of hydrocarbons from geological formations, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Sampling of hydrocarbons from geological formations will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3606902

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.