Chemistry: analytical and immunological testing – Including sample preparation – Volumetric liquid transfer
Reexamination Certificate
2001-06-15
2004-09-14
Snay, Jeffrey R. (Department: 1743)
Chemistry: analytical and immunological testing
Including sample preparation
Volumetric liquid transfer
C422S105000, C141S002000, C141S130000, C141S260000, C141S018000, C073S864240, C073S864340
Reexamination Certificate
active
06790674
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention relates to methods and apparatus for sampling liquids under conditions that maximize precise analysis of ingredients.
In one class of methods and apparatuses for sampling liquids, the apparatus automatically draws samples of known amounts of liquids at preprogrammed intervals and deposits them into containers, which are usually bottles. The prior art automatic samplers of this class fill open containers. This type of automatic sampler has a disadvantage if used to sample liquids with volatile materials in them because substantial amounts of the volatile materials escape before measurement.
Another class of sampler includes containers that can be opened to receive liquid and closed after filling without air space within them to preserve as much of the volatile materials that are within the liquid before being drawn as possible. A prior art type of sampler of this class includes a valve in an inlet conduit and a valve in an outlet conduit. This type of valve has a disadvantage in that it is difficult to automate because of the number and types of valves, the size of the valves and the size of the plumbing associated with the valves. A system of this type is disclosed in U.S. Pat. Nos. 4,974,456 and 4,864,877.
SUMMARY OF THE INVENTION
Accordingly, it is an object of the invention to provide a novel liquid sampler.
It is a further object of the invention to provide a novel automatic liquid sampler that can preserve representative samples of liquids having volatile materials in them.
It is a still further object of the invention to provide sample containers having a single opening that serves as the inlet port, overflow port and as a closure for the containers wherein there is no air space and only liquid in a filled container after sampling.
It is a still further object of the invention to provide a novel sampler that automatically draws samples and deposits them in containers with no air space in the containers.
It is a still further object of the invention to provide a novel sampler that does not release volatile materials from the liquid so that the liquid in the container is representative of the sampled liquid.
It is a still further object of the invention to provide a volatile liquid sampling system that only requires one valve for each container to fill it so that there is substantially no air space.
It is a still further object of the invention to provide an automatic sampling system in which a needle is passed through a valve opening to fill the container to overflowing and then withdrawn, with the valve opening being closed immediately upon withdrawal.
It is a still further object of the invention to provide a sample collecting system in which a needle is within a socket with a portion of it sealing a central outlet of the socket while the lines are purged and then the needle moves through the central opening of the socket into a bottle cap connector and valve opening to deposit a sample in a container.
It is a still further object of the invention to provide an automatic sampling system that samples hot liquids without losing volatile materials through bubbling.
In accordance with the above and further objects of the invention, a filling station sequentially fills sample containers by moving a hollow needle into each container in sequence and completely filling each container with liquid. The needle is moved into each container by moving it through a valve dedicated to that container. After purging air from the container where this is part of the procedure, the needle is withdrawn, preferably from near the bottom of the container, as liquid flows: (1) radially outwardly from the needle to sweep bubbles from the walls of the container and needle; and (2) under the liquid in the container to avoid turbulence that otherwise could release volatile compounds.
As the needle approaches the valve before filling, the valve begins to open and a fluid socket closes the bottle cap. The shank of the needle and an end ball or plug on the end of the needle slide through the fluid socket, a cavity on the bottle cap and through the valve opening. It proceeds to a location near the bottom of the container and injects sample. The bottle may be filled with liquid for displacing air and the needle withdrawn, with liquid continuing to flow as it is withdrawn. As the needle is withdrawn, the valve outlet closes. The opening and closing of the valve, the movement of the hollow needle, the insertion and removal of the socket from a connector in the bottle, the pumping of liquid and the movement of bottles into and from a filling station are all synchronized to provide samples precisely representing the liquid in the aquafer or other body of water, or other liquid being sampled.
In the preferred embodiment, the valve closes by rotating, with the valve being opened when the valve inlet is facing upwardly toward the needle, and being closed when it turns so that it is sideways. Just before the needle tip is inserted, during the time the container is being filled and for a short period of time after the needle is withdrawn, the fluid socket closes the container cap and any overflow liquid flows out of the connector. As the valve closes, there is a head of liquid above the valve so that no space for air or other gas is possible in the closed container.
When the socket is over the cap of a container with the needle extending through the valve opening, the socket seals the cavity in the cap and liquid fills the container from the needle. Liquid overflowing the container passes through the valve and into the socket where it leaves the outlet port. When the container has been filled and the needle withdrawn through the container valve opening to seal the central outlet of the socket, the socket can be withdrawn without releasing liquid to fall in the container.
At programmed intervals, different containers and at least one sampling station are moved with respect to each other and samples are taken to fill the containers. The containers are filled so that there is no head space and minimum loss of volatile compounds. Preferably, the containers are standard sample bottles. The containers are preferably open to the atmosphere for no more than a few seconds and should not be open for more than ten minutes during the entire operation to avoid contamination.
In some applications, samples are taken from liquid bodies at high temperatures. It has been found that upon cooling in a closed container, bubbles are formed, probably because a vacuum is formed in the sample bottles by the contraction of the liquid upon cooling. The vacuum may pull volatiles from the liquid to form bubbles. To prevent the formation of bubbles, samples are cooled before being sealed in the sample bottles or other container.
From the above description, it can be understood that the sampler of this invention has several advantages, such as: (1) it is completely automatic; (2) it can draw samples without substantial release of volatile compounds; (3) it can draw samples at predetermined intervals without human intervention; (4) a single valve permits the flow into a sample container, overflow from the container during purging of air and collection of the sample liquid in the container; (5) the liquid enters the containers with little turbulence that otherwise would cause the volatile compounds to be released before the container is filled and sealed; (6) samples drawn from hot bodies of liquid are cooled to reduce the incidence of bubbles of volatile materials being formed in the closed containers; and (7) the containers are completely filled with sample without head space.
REFERENCES:
patent: 2665585 (1954-01-01), Marcell et al.
patent: 3093165 (1963-06-01), Risser
patent: 3105527 (1963-10-01), Mayeux
patent: 3589410 (1971-06-01), Manas
patent: 3603471 (1971-09-01), Harris et al.
patent: 3757981 (1973-09-01), Harris et al.
patent: 3896673 (1975-07-01), Audouze et al.
patent: 4257751 (1981-03-01), Kofahl
patent: 4517851 (1985-05-01), Tice
patent: 4525979 (1985-07-01), Lin et al.
patent: 4674343
Busboom Paul Thees
Foley Jack William
Fritz Larry Lee
Hull John D.
Kazakevicius Jerome John
Carney Vincent L.
Isco, Inc.
Snay Jeffrey R.
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