Compositions: ceramic – Ceramic compositions – Glass compositions – compositions containing glass other than...
Patent
1995-09-21
1999-09-21
Marcantoni, Paul
Compositions: ceramic
Ceramic compositions
Glass compositions, compositions containing glass other than...
501 38, 501 951, C03C 1306
Patent
active
059553898
ABSTRACT:
A saline soluble fiber is disclosed that is highly refractory. A vacuum cast perform of the fiber has a shrinkage of 3.5% or less when exposed to 1260.degree. C. for 24 hours. The fiber may comprise CaO, SiO.sub.2, MgO, optionally ZrO.sub.2, optionally less than 0.75 mol % Al.sub.2 O.sub.3, any incidental impurities amounting to less than 2 mol % in total, and in which the SiO.sub.2 excess (defined as the amount of SiO.sub.2 calculated as remaining after the above named constituents are crystallized as silicates) exceeds 21.8 mol %, with the proviso that, if the amount of CaO is greater than the sum of the amount of MgO and twice the amount of ZrO.sub.2 the calculated ratio of diopside to wollastonite does not lie in the range 0.1 to 5.22. Such fibers are usable at elevated temperatures where refractoriness is of importance and their solubility in saline solution may make the fibers safer than non-soluble fibers.
REFERENCES:
patent: 2051279 (1936-08-01), Thorndyke
patent: 2116303 (1938-05-01), Coss
patent: 2155107 (1939-04-01), Tyler et al.
patent: 2308857 (1943-01-01), Bowes
patent: 2428810 (1947-10-01), Powell
patent: 2520168 (1950-08-01), Powell
patent: 2520169 (1950-08-01), Powell
patent: 2576312 (1951-11-01), Minnick
patent: 2577431 (1951-12-01), Powell
patent: 2823416 (1958-02-01), Powell
patent: 3348956 (1967-10-01), Ekdahl
patent: 3449137 (1969-06-01), Ekdahl
patent: 3799836 (1974-03-01), Tomic et al.
patent: 3887386 (1975-06-01), Majumdar
patent: 4036654 (1977-07-01), Yale et al.
patent: 4054472 (1977-10-01), Kondo et al.
patent: 4055434 (1977-10-01), Chen et al.
patent: 4153439 (1979-05-01), Tomic et al.
patent: 4205992 (1980-06-01), Mogensen et al.
patent: 4238213 (1980-12-01), Pallo et al.
patent: 4251279 (1981-02-01), Ekdahl
patent: 4274881 (1981-06-01), Langton et al.
patent: 4325724 (1982-04-01), Froberg
patent: 4342581 (1982-08-01), Neubauer et al.
patent: 4351054 (1982-09-01), Olds
patent: 4366251 (1982-12-01), Rapp
patent: 4377415 (1983-03-01), Johnson et al.
patent: 4437192 (1984-03-01), Fujiu et al.
patent: 4443550 (1984-04-01), Kume et al.
patent: 4482541 (1984-11-01), Telfer et al.
patent: 4555492 (1985-11-01), Ekdahl et al.
patent: 4615988 (1986-10-01), Le Moigne et al.
patent: 4661134 (1987-04-01), Hartung
patent: 4678659 (1987-07-01), Drake et al.
patent: 4693740 (1987-09-01), Noiret et al.
patent: 4957559 (1990-09-01), Tiesler et al.
patent: 5023552 (1991-06-01), Nonami et al.
patent: 5055428 (1991-10-01), Potter
patent: 5108957 (1992-04-01), Cohen et al.
patent: 5121748 (1992-06-01), Ditz et al.
patent: 5217529 (1993-06-01), Tiesler et al.
patent: 5248637 (1993-09-01), Taneda et al.
patent: 5250488 (1993-10-01), Thelohan et al.
patent: 5312806 (1994-05-01), Mogensen
patent: 5332699 (1994-07-01), Olds et al.
patent: 5401693 (1995-03-01), Bauer et al.
"Fiber Glass,"J. Mohr and W. Rowe, Van Nostrand Reinhold Company, publishers pp. 4-23 (1978).
"Preparation and Properties of Barium Ferrite Using Hot-Rolled Mill Scale," Chien, Yung-Tsen, et al., J. Am. Ceram. Soc., vol. 72, No. 8, pp. 1328-1332 (1989).
"Advertisement for the Sale of a Fiber Glass Blanket Under the Name New Super Wool.TM.," published (Jan. 1987).
"the Dissolution of Asbestos Fibres in Water," Gronow, J., Clay Minerals, vol. 22, pp. 21-35 (1987).
"Man-Made Vitreous Fibers: An Overview of Studies on their Biologic Effects," Gross, P., Am. Ind. Hyg. Assoc. J., vol. 47, No. 11, 717-723 (1986).
"Solubility of Asbestos and Man-Made Fibers In Vitro and In vivo: Its Significance in Lung Disease," Morgan, A., et al., Environmental Research, vol. 39, pp. 475-484 (1986).
"Corrosion Phenomena in Glass Fibers and Glass Fiber Reinforced Thermosetting Resins," Bledzki, A. et al., Composites Science & Technology, Harris and Chou, eds., Elsevier Applied Science Publishers, vol. 23, pp. 263-285 (1985).
"Fiber Toxicology," Leineweber, J.P., J. Occupational Medicine, vol. 23, No. 6, pp. 431-434 (1981).
"Development of a Deoiling Process for Recycling Millscale," Recycling in the Steel Industry, Proceedings of the 1st Process Technology Conference, vol. 1, pp. 184-187, Washington, D.C., (Mar. 25-26. 1980).
"Effects of Glass Surface Area to Solution Volume Ration on Glass Corrosion," Ethridge, E.C. et al., Physics and Chemistry of Glasses, vol. 20, No. 2, pp. 35-40 (1979).
"Chemical Durability of Glasses in the Systems SiO.sub.2 --CaO--Na.sub.2 O--R.sub.m O.sub.n" " H. Ohta and Y. Suzuki, Ceramic Bulletin, vol. 57, No. 6, pp. 602-604 (1978).
"Glass Compositions for Glass Fibers," Moriya, Ichiro, et al., Chemical Abstracts, vol. 89, No. 22, p. 28, Abstract 184615W (1978).
"Glass for Making Glass Fiber," Grigor'ev, V.S., et al., Chemical Abstracts, vol. 81, No. 22, Abstract 140076b (1974).
"Dissolution Kinetics of Magnesium Silicates," Luce, R.W., et al., Geochimica et Cosmochimica Acta., vol. 36, pp. 35-50 (1972).
"Elements of Ceramics," Norton, F.H., Addison-Wesley Publishing Co., Inc., p. 39 Reading, Massachusetts (1952).
"The behaviour of mineral fibres in physiological solutions" H. Forster Proceedings of 1982 WHO IARC Conference, Copenhagen, vol. 2, pp. 27-55 (1988).
Chemical Abstracts vol. 110 No. 10, abstract No. 81274g p. 373 (1989) (equivalent to CN-A-87 108257).
Database WPIL Section Ch. Week 8218 Class L AN 82-36551E (equivalent to JP-B-57016938).
"The reactions of MMMF in a physiological model fluid and in water" R. Klinghol & B. Steinkopf Proceedings of 1982 WHO IARC Conference, Copenhagen, vol. 2, pp. 61-86 (1988).
"Solubility of fibres in vitro and in vivo" J.P. Leinweber Proceedings of 1982 WHO IARC Conference, Copenhagen, vol. 2, pp. 87-101 (1988).
"In vitro study on siliceous fibres" H. Scholze & R. Conradt Proceedings of 198 WHO IARC Conference.
"An in vitro Study of the Chemical Durability of Siliceous Fibres" H. Scholze & R. Conradt Annals of Occupational Hygiene 31,4B(1987) 683-692.
"Chemical Durability of asbestos and of man-made minderal fibres in vivo" B. Bellman et al. Aerosol Scientist Vo. 17 No. 3 pp. 341-345, 1986.
Brochure showing Manville Corporation Superwool product (two pages).
Brochure showing Morgan Crucible Company Superwool product (two pages) (No Date Available).
Brochures showing Carborundum Company Insulfrax product (sixteen pages) (No Date Available).
"A scale of acidity and basicity in glass"--Glass Industry, Kuan-Han Sun (1948).
"Encyclopedia of Chemical Technology" Kirk & Othmer vol. 9, p. 124 "Mineral Wool" (1952).
US Bureau of Mines Circular "Mineral Wool" I.C. 698R dated Jun. 1939.
"Slag Wools" pp. 111-127 Inorganic Fibres (No Date Available).
"Chemical Durability" Chapter 34 of "Glass Science and Technology", Elsevier, 1988.
"Thermodynamic model of natural, medieval and nuclear waste glass durability" C. Jantzen & M.J. Plodinec Journal of Non-Crystalline Solids 67(1984) 208-233.
"Stability of Radioactive Waste Glasses Assessed from Hydration Thermodynamics" M.J. Plodinec, C.M. Jantzen, & G.G. Wicks pp. 755-762 (1984).
Nuclear Waste Glass Durability: 1, Predicting Environmental Response from thermodynamic (Pourbaix) Diagrams Carol M. Jantzen Journal of American
"Prediction of Nuclear waste Glass Durability from Natural Analogs" C.M. Jantzen Advances in Ceramics vol. 20: Nuclear Waste Management II (1986).
"Prediction of Glass Durability as a Function of Glass Composition and test Conditions: Thermodynamics and Kinetics" C.M. Jantzen Advances in the Fusion of Glass 24.1-24.17 (No Date Available).
"A new approach to predicting the durability of glasses from their chemical
"Glass-water interactions" H. Scholze Journal of Non-Crystalline Solids 102(1988) 1-10.
"Chemical durability of Glass" Chapter 6 from "Chemistry of Glasses" 2nd edition A. Paul (1990).
Brochure re PARGAS-Platten 1000.degree. C. mineral wool plates (three pages) (No Date Available).
"Inviscid spinning of Filaments via Chemical Jet Stabilization" R.E. Cunningham, L.F. Rakestraw & S.A. Dunn American Institute of Chemical Engineers Symposium Series No. 180 vol. 74,20-31 (1978).
"Low-cost Reinforcing Fibres Promise a High Level of Performance" S.A. Dunn, Modern Plastics International, (1989) 50-51.
"Ca
Gray Bruce D.
Marcantoni Paul
Russell Dean W.
The Morgan Crucible Company, p/c
LandOfFree
Saline soluble inorganic fibres does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Saline soluble inorganic fibres, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Saline soluble inorganic fibres will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-79972