Compositions: ceramic – Ceramic compositions – Glass compositions – compositions containing glass other than...
Patent
1997-09-24
1999-07-27
Marcantoni, Paul
Compositions: ceramic
Ceramic compositions
Glass compositions, compositions containing glass other than...
501 38, C03C 1306
Patent
active
059289759
ABSTRACT:
A saline soluble fiber is disclosed that is highly refractory. A vacuum cast preform of the fiber has a shrinkage of 3.5% or less when exposed to 1260.degree. C. for 24 hours. The fiber may comprise CaO, SiO.sub.2, MgO, optionally ZrO.sub.2, optionally less than 0.75 mol % Al.sub.2 O.sub.3, any incidental impurities amounting to less than 2 mol % in total, and in which the SiO.sub.2 excess (defined as the amount of SiO.sub.2 calculated as remaining after the above named constituents are crystallized as silicates) exceeds 21.8 mol %, with the proviso that, if the amount of CaO is greater than the sum of the amount of MgO and twice the amount of ZrO.sub.2 the calculated ratio of diopside to wollastonite does not lie in the range 0.1 to 5.22. Such fibers are usable at elevated temperatures where refractoriness is of importance and their solubility in saline solution may make the fibers safer than non-soluble fibers.
REFERENCES:
patent: 2051279 (1936-08-01), Thorndyke
patent: 2116303 (1938-05-01), Coss
patent: 2155107 (1939-04-01), Tyler et al.
patent: 2308857 (1943-01-01), Bowes
patent: 2428810 (1947-10-01), Powell
patent: 2520168 (1950-08-01), Powell
patent: 2520169 (1950-08-01), Powell
patent: 2576312 (1951-11-01), Minnick
patent: 2577431 (1951-11-01), Powell
patent: 2823416 (1958-02-01), Powell
patent: 3348956 (1967-10-01), Ekdahl
patent: 3449137 (1969-06-01), Ekdahl
patent: 3799836 (1974-03-01), Tomic et al.
patent: 3887386 (1975-06-01), Majumdar
patent: 4036654 (1977-07-01), Yale et al.
patent: 4054472 (1977-10-01), Kondo et al.
patent: 4055434 (1977-10-01), Chen et al.
patent: 4153439 (1979-05-01), Tomic et al.
patent: 4205992 (1980-06-01), Mogensen et al.
patent: 4238213 (1980-12-01), Pallo et al.
patent: 4251279 (1981-02-01), Ekdahl
patent: 4274881 (1981-06-01), Langton et al.
patent: 4325724 (1982-04-01), Froberg
patent: 4342581 (1982-08-01), Neubauer et al.
patent: 4351054 (1982-09-01), Olds
patent: 4366251 (1982-12-01), Rapp
patent: 4377415 (1983-03-01), Johnson et al.
patent: 4437192 (1984-03-01), Fujiu et al.
patent: 4443550 (1984-04-01), Kume et al.
patent: 4482541 (1984-11-01), Telfer et al.
patent: 4555492 (1985-11-01), Ekdahl et al.
patent: 4615988 (1986-10-01), Le Moigne et al.
patent: 4661134 (1987-04-01), Hartung
patent: 4678659 (1987-07-01), Drake et al.
patent: 4693740 (1987-09-01), Noiret et al.
patent: 4957559 (1990-09-01), Tiesler et al.
patent: 5023552 (1991-06-01), Nonami et al.
patent: 5055428 (1991-10-01), Potter
patent: 5108957 (1992-04-01), Cohen et al.
patent: 5121748 (1992-06-01), Ditz et al.
patent: 5217529 (1993-06-01), Tiesler et al.
patent: 5248637 (1993-09-01), Taneda et al.
patent: 5250488 (1993-10-01), Thelohan et al.
patent: 5312806 (1994-05-01), Mogensen
patent: 5332699 (1994-07-01), Olds et al.
Database WPIL Section Ch. Week 8218, Class L AN 82-36551E (equivalent to JP-B-57016938).
Brochure showing Manville Corporation Superwool Product (two pages).
Brochure showing Morgan Crucible Company Superwood Product (two pages).
Brochure showing Carborundum Company Insulfrax Product (sixteen pages).
Brochure re: PARGAS-Platten 1000.degree.C Mineral Wool Plates (three pages).
"Fiber Glass," J. Mohr and W. Rowe, pp. 4-23.
"Prediction of Glass Durability as a Function of Glass Composition and Test Conditions . . . " C.M. Jantzen, Advances in the Fusion of Glass, 24.1-24.17.
"Stability of Radioactive Waste Glasses Assessed from Hydration Thermodynamics," M.J. Plodinec, C.M. Jantzen, and G.G. Wicks.
"Nuclear Waste Glass Durability: 1, Predicting environmental Response from thermodynamic (Pourbaix) Diagrams," Carol M. Jantzen, Journal of American Ceramic Society, 75(9):2433-2448 (1992).
"Calcium Aluminate Glass Fibres: Drawing from Supercooled Melts Versus Inviscid . . . ," F.T. Wallenberger et al., Materials Letters,, 11:229-235 (1991).
"Chemical Durability of Glass," Chemistry of Glasses, Chapter 6, 2nd Edition, A. Paul (1990).
Chemical Abstracts, 110(10):373, Abstract No. 81274g, (equivalent to CN-A-87 108257) (1989).
"Low-Cost Reinforcing fibres Promise a High Level of Performance," S.A. Dunn, Modern Plastics International, pp. 50-51 (1989).
"Preparation and Properties of Barium Ferrite Using Hot-Rolled Mill Scale," Chien, Yung-Tsen, et al., J. Am. Ceram. Soc., vol. 72, No. 8, pp. 1328-1332 (1989).
"The Behaviour of Mineral Fibres in Physiological Solutions," H. Forster, Proceedings of 1982 WHO IARC Conference, Copenhagen, vol. 2, pp. 27-55 (1988).
"Chemical Durability," Glass Science and Technology, Chapter 34, Elsevier (1988).
"Glass-Water Interactions," H. Scholze, Journal of Non-Crystalline Solids, 102:1-10 (1988).
"The Reactions of MMMF in a Physiological Model Fluid and in Water," R. Klingholz & B. Steinkopf, Proceedings of 1982 WHO IARC Conference, Copenhagen, vol. 2, pp. 87-101 (1988).
"Solubility and Durability of Manmade Mineral Fibers in Physiological Fluids," J. Bauer, et al., (nineteen pages; dated no later than 1988).
Standard Test Methods for Fire Tests of Building Construction and Materials (ASTM) E119-88) (fourteen pages; 1988).
"Advertisement for the Sale of a Fiber Glass Blanket Under the Name New Super Wool.TM.," published after Sep. 1986 (on or about Jan. 1987).
"An in vitro Study of the Chemical Durability of Siliceous Fibres," H. Scholze & R. Conradt, Annals o fOccupational Hygiene, 31, 4B, pp. 683-692 (1987).
"The Dissolution of Asbestos Fibres in Water," Gronow, J., Clay Minerals, vol. 22, pp. 21-35 (1987).
"In vitro Study on Siliceous fibres," H. Scholze & R. Conradt, Proceedings of 1986 WHO IARC Conference.
"Chemical Durability of Asbestos and of Man-made Minderal Fibres in vivo," B. Bellman et al., Aerosol Scientist, vol. 17, No. 3, pp. 341-345 (1986).
"Man-Made Vitreous Fibers: An Overview of Studies on Their Biologic Effects," Gross, P., Am. Ind. Hyg. Assoc. J., vol. 47, No. 11, 717-723 (1986).
"Prediction of Nuclear Waste Glass Durability from Natural Analogs," C.M. Jantzen, Advances in Ceramics, vol. 20, Nuclear Waste Management II (1986).
"Solubility of Asbestos and Man-Made Fibers In Vitro and In Vivo: Its Significance in Lung Disease," Morgan, A., et al., Environmental Research, vol. 39, pp. 475-484 (1986).
"Multicomponent Silicate Glasses," Molecular Structure, pp. 28-31.
"Corrosion Phenomena in Glass Fibers and Glass Fiber Reinforced Thermosetting Resins," Bledzki, A. et al., Composites Science & Technology, Harris and Chou, eds., Elsevier Applied Science Publishers, vol. 23, pp. 263-285 (1985).
"Thermodynamic Model of Natural, Medieval and Nuclear Waste Glass Durability," C.M. Jantzen et al., Journal of Non-Crystalline Solids, 67:208-233 (1984).
"Fiber Toxicology," Leineweber, J.P., J. Occupational Medicine, vol. 23, No. 6, pp. 431-434 (1981).
"A New Approach to Predicting the Durability of Glasses from Their Chemical Compositions," R.G. Newton and A. Paul, Glass Technology, 21(6):307-309 (1980).
"Development of a Deoiling Process for Recycling Millscale," Recycling in the Steel Industry, Proceedings of the 1st Process Technology Conference, vol. 1, pp. 184-187, Washington, D.C., (Mar. 25-26, 1980).
"Effects of Glass Surface Area to Solution Volume Ration on Glass Corrosion," Ethridge, E.C. et al., Physics and Chemistry of Glasses, vol. 20, No. 2, pp. 35-40 (1979).
"Glass Compositions for glass Fibers," Moriya, Ichiro, et al., Chemical Abstracts, vol. 89, No. 22, p. 28, Abstract 184615W (1978).
"Inviscid Spinning of Filaments via Chemical Jet Stabilization," R.E. Cunningham, L.F. Rakestraw and S.A. Dunn, American Institute of Chemical Engineers Symposium Series, No. 180, vol. 74, 20-31 (1978).
"Chemical Durability of Glasses in the Systems SiO.sub.2 -CaO-Na.sub.2 O-R.sub.m O.sub.n,," H. Ohta and Y. Suzuki, Ceramic Bulletin, vol. 57, No. 6, pp. 602-604 (1978).
"Glass for Making Glass Fiber," Grigor'ev, V.S., et al., Chemical Abstracts, vol. 81, No. 22, Abstract 140076b (1974).
"Dissolution Kinetics of Magnesium Silicates," Luce, R.W., et al., Geochimica et Cosmochimica Acta., vol. 36, pp. 35-50 (1972).
"A Scale of Acidity and Basicity in Glass," Glass Industry, Kuan-Han Sun (1948).
"Elements of Ceramics," Norto
Gray, Esq. Bruce D.
Marcantoni Paul
Russell, Esq. Dean W.
The Morgan Crucible Company,plc
LandOfFree
Saline soluble inorganic fibers does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Saline soluble inorganic fibers, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Saline soluble inorganic fibers will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-878345