Rutile titania nano sols and process for manufacturing the same

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C423S608000, C423S579000, C423S592100

Reexamination Certificate

active

07611688

ABSTRACT:
The present invention is related to a process of manufacturing rutile high-purity titania nano sols in a pure aqueous medium having no ionic impurities. In more detail, the present invention is related to a process for manufacturing titania nano sols, in which high-purity rutile titania nano particles are dispersed stably, through the hydrolysis of titanium tetraisopropoxide in an aqueous solution containing hydrogen peroxide (H2O2), and simultaneously with the hydrolysis, formation of peroxotitanate precursors, and hydrothermal treatment of them at 50-120° C.

REFERENCES:
patent: 5051183 (1991-09-01), Takita et al.
patent: 6440383 (2002-08-01), Duyvesteyn et al.
patent: 7304106 (2007-12-01), Brady et al.
patent: 2006/0110319 (2006-05-01), Seok et al.
patent: 62-283817 (1987-12-01), None
patent: 10212121 (1998-08-01), None
patent: 200158825 (2001-03-01), None
patent: 2001-172019 (2001-06-01), None
patent: 2000-0066290 (2000-11-01), None
patent: 1020040007586 (2004-01-01), None
Uekawa et al. “Synthesis of rutile and anatase TiO2 nanoparticles with Ti-peroxy compound aqueous solution with polyols”. J. Mater. Res., vol. 18, No. 4, Apr. 2003.
“Rutile Formation in Hydrothermally Crystallized Nanosized Titania”; Authors: Revathi R. Bacsa and Michael Gratzel; J. Am. Ceram. Soc., 79 (8), 2185-88 (1996).
Sol-Gel Synthesis and Hydrothermal Processisng of Anatase and Rutile Titania Nanocrystals; Authors: Chen-Chi Wang and Jackie Y. Ying; Che, Mater., 11,3113-3120 (1999).
“Nanosize Rutile Titania Particle Synthesis Via a Hydrothermal Method Without Mineralizers”; Authors: S. T. Aruna, S. Tirosh and A. Zaban; J. Mater. Chem., 10-2388-2391 (2000).
“A Novel Method for Preparation of Nanocrystallilne Rutile TiO2 Powders by Liquid Hydrolysis of TiC14”; Authors: Yuanzhi Li, Yining Fan and Yi Chen; J. Mater. Chem., 12, 1387-1390 (2002).
“Homogeneous Precipitaiton of TiO2 Ultrafine Powders Form Aqueous TiOCI2 Solution”; Authors: Sun-Jae Kim, Soon-Dong Park, and Yong Hwan Jeong; J. Am. Ceram. Soc., 82, 927 (1999).
Synthesis of Rutile (a-TiO2) Nanocrystals With Controlled Size and Shape by Low-Temperature Hydrolysis: Effects of Solvent Composition; Authors: Wei Wang, Baohua Gu, Liyuan Liang, William A. Hamilton, and David J. Wesolowski; J. Phys. Chem. B. 108, 14789 (2004).
“Properties of Anatase Films for Photocatalyst From Peroxotitanic Acid Solution and Peroxo-Modified Anatase Sol”; Hiromichi Ichinoise, Akihiko Kawahara and Hiroaki Katsuki; J. Ceram. Soc. Jpn., 104, 715 (1996).
Fedii, A. A.; Lukshina, S. N.; Sadykov, R. M.; Sablina, E. V. Effect of antimony oxide additives on the properties of titanium dioxide containing iron and chromium oxides as impurities. Lakokrasochnye Materialy i Ikh Primenenie (1989), (1), 10-12. CODEN: LAMAAD ISSN:0023-737X. CAN 111:99007 AN 1989:499007 CAPLUS.
Berry, Frank J.; Gogarty, Patricia M. An investigation of phases in the titanium—antimony -oxygen system. Inorganica Chimica Acta (1988), 141(1), 53-6. CODEN: ICHAA3 ISSN:0020-1693. CAN 108:123195 AN 1988:123195 CAPLUS.
Eppler, Richard A. Effect of antimony oxide on the anatase—rutile transformation in titanium dioxide. Journal of the American Ceramic Society (1987), 70(4), C/64-C/66. CODEN: JACTAW ISSN:0002-7820. CAN 106:181304 AN 1987:181304 CAPLUS.
Sheinkman, A. I.; Gol'dshtein, L. M.; Turlakov, V. N.; Kleshchev, G. V. Phase formations during the interaction of antimony oxides with hydrated titanium dioxide. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation) (1972), 45(5), 940-4. CODEN: ZPKHAB ISSN:0044-4618. CAN 77:67154 AN 1972:467154 CAPLUS.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Rutile titania nano sols and process for manufacturing the same does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Rutile titania nano sols and process for manufacturing the same, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Rutile titania nano sols and process for manufacturing the same will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4086990

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.