Ruthenium-rhenium catalyst on titania support for Fischer-Tropsc

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502350, 518715, B01J 2106, B01J 2364

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active

045580308

ABSTRACT:
A novel ruthenium catalyst, notably a ruthenium-titania catalyst, is disclosed to which is added sufficient rhenium to obtain, at corresponding process conditions, improved activity maintenance in the production of hydrocarbons via carbon monoxide-hydrogen synthesis reactions vis-a-vis a catalyst composition otherwise similar except that it does not contain rhenium. High quality middle distillate fuels, characterized generally as admixtures of linear paraffins and olefins, are formed in a process wherein a feed mixture of carbon monoxide and hydrogen are contacted at reaction conditions over such catalyst.

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Fischer-Tropsch Synthesis Over Titania-Supported Ruthenium Catalysts; Kikuchi, Matsumoto, Takahashi, Machino and Morita (Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, Japan); Printed in the Netherlands; Applied Catalysis, 10 (1984), pp. 251-260.
IS-T-1006; Hydrogenation of Carbon Monoxide Over Ruthenium-Rhenium on Alumina Catalysts; D. E. Whitmoyer (M.S. Thesis Submitted to Iowa State University); Prepared for the U.S. Department of Energy Under Contract No. W-7405-Eng-82; Jul. 1982.

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