Ruthenium hydrogenation catalysts

Details Ruthenium hydrogenation catalysts Ruthenium hydrogenation catalysts

1996-05-08

1997-11-18

Nazario-Gonzalez, Porfirio

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

556 21, 556 22, 556 23, 556136, 564490, 564491, 564492, 564493, 564494, 568840, C07C20948, C07C20932, C07F 1500

Patent

active

056890036

ABSTRACT:
The invention relates to a novel ruthenium complex having the formula Ru(.eta..sup.3 --C.sub.6 H.sub.8 --PCy.sub.2)(PCy.sub.3)Cl, wherein Cy is cyclohexyl; its use in the preparation of RuHCl(H.sub.2)(PCy.sub.3).sub.2 and RuH.sub.2 (H.sub.2).sub.2 (PCy.sub.3).sub.2 ; and the use of the complexes as catalysts in hydrogenation, imination and reductive hydrolysis processes.

REFERENCES:
patent: 3454644 (1969-07-01), Dewhirst
patent: 4362671 (1982-12-01), Diamond et al.
patent: 4482760 (1984-11-01), Kleeman et al.
patent: 4810825 (1989-03-01), Matsushita et al.
patent: 5151543 (1992-09-01), Ziemecki
Chaudret, B. et al, Organometallics, 4, 1722-1726 (1985).
Chaudret, B. et al, J. Am. Chem. Soc., 113, 2314-2316 (1991).
Joshi, A.M. et al, Prog. in Catal., 73, 143-146 (1992).
Arliguie, T. et al, Organometallics, 10, 1888 (1991).
Armit, P.W. et al, J. Chem. Soc., Dalton Transactions, pp. 1663-1672 (1975).
Christ, M.L. et al, Organometallics, 13, 3800-3804 (1994).
Joshi, A. N. et al, Inorg. Chim. Acta, 198-200; 283-296 (1992).
Dehmlow, E.V., Universitat Bielefeld, Germany, Kirk-Othmer Encyclopedia of Chem. Tech., 4th Ed., 5, 374-383 (1993).
Grushin, V.V., Acc. Chem. Res., 26, 279-286 (1993).
Albers, M.O. et al, Inorganic Syntheses, 26, 68-77 (1989).
Suarez, T. et al, J. Mol. Cat., 45, 335 (1988).
Mizzoni, R.H. et al, J. Med. Chem., 13(5), 878-882 (1970).
Yosida, T. et al, JCS Chem. Commun., 870-871 (1979).

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