Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing
Patent
1998-10-28
2000-12-12
Bell, Mark L.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Organic compound containing
502158, 502172, 502169, 502156, B01J 3100
Patent
active
061598909
ABSTRACT:
A ruthenium-containing metathesis catalyst system which contains a ruthenium compound (A), a phosphorus, arsenic, or antimony compound (B), and a compound (C) containing at least one carbon-to-carbon triple bond. The mole ratio of compounds A:B:C is typically in the range of about 1.0:0.01-100:0.01-500. The ruthenium compound (A) is a Ru(II), Ru(III), or Ru(IV) compound containing an anionic ligand (X) and optionally an arene ligand and optionally a phosphorus, arsenic, or antimony compound ligand. The compound (B) is optional if the ruthenium compound (A) contains a phosphorus-, arsenic-, or antimony-containing ligand. Hydrogen gas is used as an activator. A process for metathesis of olefins involves reacting at least one olefin with the catalyst system described herein.
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Choi David S.
Hunt Craig Lane
Marks Tobin J.
Nubel Philip O.
Bell Mark L.
BP Amoco Corporation
Henes James R.
Oliver Wallace L.
Pasterczyk J.
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