Ruthenium-cobalt carbonyl metal cluster catalysts for the dealko

Details Ruthenium-cobalt carbonyl metal cluster catalysts for the dealko Ruthenium-cobalt carbonyl metal cluster catalysts for the dealko

1985-10-02

1986-10-21

Helfin, Bernard

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568648, 568664, 568665, 568670, 568649, C07C 4128, C07C 4118

Patent

active

046187294

ABSTRACT:
The ruthenium-cobalt carbonyl metal cluster catalyst Co.sub.2 Ru(CO).sub.11 effectively catalyzes the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of this ruthenium-cobalt cluster catalyst to form the monomethyl ether of ethylene glycol.

REFERENCES:
patent: 4062898 (1977-12-01), Dubeck et al.
patent: 4079085 (1978-03-01), Wall
patent: 4357477 (1982-11-01), Knifton
patent: 4390734 (1983-06-01), Knifton

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