Chemistry of inorganic compounds – Carbon or compound thereof – Oxygen containing
Patent
1981-06-16
1982-09-14
Thomas, Earl C.
Chemistry of inorganic compounds
Carbon or compound thereof
Oxygen containing
423418, 260429R, C01G 104, C01G 5500, C07F 1500
Patent
active
043495214
ABSTRACT:
Disclosed are the novel cluster compounds [HRu.sub.4 (CO).sub.13 ].sup.1-, [Ru.sub.4 (CO).sub.13 ].sup.2-, [Ru.sub.4 (CO).sub.12 ].sup.4-, [HRu.sub.4 (CO).sub.12 ].sup.3-, and salts thereof, and H.sub.4 Ru.sub.4 (CO).sub.12. Also disclosed are novel procedures for synthesizing these cluster compounds in high yield. Further disclosed is a novel procedure for making H.sub.2 Ru.sub.4 (CO).sub.13 and H.sub.4 Ru.sub.4 (CO).sub.12 in high yield. Also disclosed are [Ru.sub.3 (CO).sub.11 ].sup.2- and the corresponding osmium dianion.
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Nagel Colleen C.
Shore Sheldon G.
The Ohio State University Research Foundation
Thomas Earl C.
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