Ruggedized ion-responsive electrode and its manufacturing proces

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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Details

204415, 204419, 29592R, G01N 2736

Patent

active

044591993

ABSTRACT:
An ion-sensitive electrode, usable for measuring the activity or concentration of a predetermined ion in a fluid stream of an industrial process, includes a vessel partially filled with an electrolyte and fabricated with one wall portion thereof comprising a rigid, porous fritted back-up element and a relatively thin, ion-sensitive, non-porous membrane. Being preferably made of the same ion-sensitive material as the membrane, the back-up element is produced using a sintering process which results in a porous solid having maze-like passages extending randomly therethrough in all directions. One surface of the back-up element is fused to and supports a thin layer of ion-sensitive material that has been applied to the back-up element, heated to its molten working temperature and then cooled to form the non-porous membrane. Located within the vessel, the back-up element also serves to transport the electrolyte through its passages for wetting the interior surface of the thin membrane fused to the back-up element. The exterior surface of the membrane is in contact with the fluid stream so that an electrical potential responsive to the activity or concentration of the pre-determined ion can be developed across the membrane.

REFERENCES:
patent: 2117596 (1938-05-01), Bender et al.
patent: 3582474 (1971-06-01), Hair et al.
patent: 3607702 (1971-09-01), Haller
patent: 3717565 (1973-02-01), Doyle
patent: 3855098 (1974-12-01), Fletcher

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