Rubbery polymers containing tin coupling agents and rubber...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

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C525S195000, C525S359300, C525S370000, C526S176000, C526S335000, C526S340000, C524S572000, C152S450000

Reexamination Certificate

active

11682027

ABSTRACT:
The present invention is directed to rubbery polymers, such as polybutadiene rubber or styrene-butadiene rubber, that contain tin coupling agents and provide desirable dispersion of carbon black in rubber compounds, such as for use in tire treads. The tin coupling agents are defined by the general formulas (I) (X3Sn)2O or (II) (X3Sn)O—(CH2)n—O(X3Sn), wherein X is a halogen and n is 1 to 20. A method of rubbery polymer synthesis, in one embodiment, involves mixing anionically polymerizable conjugated diene monomers with optional vinyl aromatic and an anionic-polymerization initiator, i.e., an organolithium compound, to form a mixture of living polymers. A tin coupling agent is added to the mixture of living polymers effecting polymerization conditions to form the tin coupled rubbery polymer. Such tin coupled rubbery polymers can be utilized in tire tread rubbers where the rubbery polymers may provide desirable wear properties without substantially sacrificing other performance characteristics.

REFERENCES:
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patent: 6191234 (2001-02-01), Tadaki et al.
patent: 7091274 (2006-08-01), Thielen et al.
Glidwell, C., “The Structures, and Acid-Base Properties of Simple Inorganic Compounds Containing Stannyl Groups: An MNDO Study,” Chemica Scripta, 1986, vol. 26, pp. 367-371.

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