Resilient tires and wheels – Tires – resilient – Pneumatic tire or inner tube
Reexamination Certificate
1999-08-27
2003-02-25
Mulcahy, Peter D. (Department: 1713)
Resilient tires and wheels
Tires, resilient
Pneumatic tire or inner tube
C524S430000, C524S441000, C524S449000
Reexamination Certificate
active
06523590
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to a non-black rubber composition for sidewalls of pneumatic vehicle tires which contains as a polymer one or more rubber components, as a first filler at least silican as well as further processing aids and further conventional additives.
Rubber mixtures for sidewalls of pneumatic vehicle tires must fulfill high standards and requirements. They must be mechanically/dynamically very stable in order to remain intact, for example, when driving across high curb edges. Furthermore, the sidewalls of a pneumatic vehicle tire should be wear-resistant in order not to be damaged when scraping along curbs. Furthermore, they are subjected to solar radiation more than any other tire component so that the elastomer mixture must be age-resistance, respectively, must contain antioxidants. Since the sidewall, especially when the vehicle is parked, catches the eye of a passer-by, it is especially suitable as a design object. For example, it is known in the prior art to provide colorful lettering as well as colored sidewalls. For such designs, elastomer mixtures are needed which have the aforementioned properties and must be colorfast over the entire service life of a pneumatic vehicle tire.
From German patent application 34 14 438 and German Gebrauchsmuster 82 34 954.1 variations are known in which either a black sidewall is covered by a transparent elastomer layer which contains mica platelets or the entire sidewall is made of such a transparent elastomer mixture which contains mica platelets. These mica platelets, which may also have a coating of metal oxides, are supposed to impart to the elastomer matrix excellent reflective properties. However, it was found that even though a sufficient reflection could be obtained, these mixtures over time would turn yellow. Additional elastomer layers known from German patent application 34 14 438 furthermore have the disadvantage that, in addition to being produced separately, they must be applied in an additional method step onto the sidewall, which results in increased cost and time expenditure. Furthermore, layer separation between the individual layers may occur.
It is therefore an object of the present invention to produce sidewalls for pneumatic vehicle tires that, with respect to process-technological considerations, are simple to produce, have excellent reflective properties as well as a long-lasting luminous silvery coloration.
SUMMARY OF THE INVENTION
The object is inventively solved in that for 100 parts by weight of total rubber mixture, a second filler in the amount of 5 to 30 phr in the form of mica platelets, which are coated with a metal oxide, is provided whereby the mica platelets have an average platelet size of up to 2·10
−4
m, and furthermore a third filler is provided which is in the form of 0.1 to 8 phr of aluminum powder having an average particle size of up to 8·10
−5
m.
Surprisingly, such a rubber mixture for sidewalls, when vulcanized, provides an excellent reflective appearance in combination with excellent silvery shine or luminance. This property combination was not to be expected because, on the one hand, tests with rubber mixtures, containing only aluminum powder, as tire sidewalls resulted in tire sidewalls having no metallic shine (for minimal aluminum powder concentrations) or, over time, were reactive with regard to other mixture components so that the tire sidewalls would appear gray (for higher aluminum concentrations). On the other hand, tire sidewalls prepared with rubber compositions containing only mica particles coated with metal oxide as a filler would result in the aforementioned yellow discoloration. Therefore, it was so surprising to find that the inventive combination solved the problem of discoloration and, at the same time, provided an optically appealling metallic shine or luminance with excellent reflective properties.
The inventive rubber mixture or composition for tire sidewalls contains as a first filler silica, preferably in an amount of 10 to 60 phr, because silica provides excellent transparent properties and thus imparts to the vehicle tire sidewall the desired appearance. Furthermore, advantages with respect to wear are obtained. Moreover, the reinforcing action of silica is taken advantage of, whereby it was found that for concentrations >60 phr the dynamic behavior of the vulcanized tire decreased. Accordingly, this concentration, especially for tire sidewalls, should not be surpassed. Silica for use with the inventive rubber mixture is known from the prior art. For example, silica having a BET surface of 145 to 270 m
2
/g (ASTM D 5604), a CTAB number of 120 to 285 m
2
/g (ASTM D 3765), and a pore volume of 0.7 to 1.7 ml/g (DIN 66133) are to be used. For example, silica by the designation VN3 (trade name of the company Degussa) can be used.
For binding silica to the polymer system, activating agents, for example silane such as bis-3-(triethoxysilylpropyl)tetrasulfide (TESPT) or the corresponding disulfide can be used which in the context of the present invention is to be considered a conventional additive.
Furthermore, the inventive rubber mixture contains other conventional additives such as colorfast anti-aging substances, (e.g., styrene-modified phenols or di-tert.-butyl-p-kresol (BHT), softeners (e.g., phthalic acid ester) and processing agents (e.g., stearic acid, wax, fat, dispersing agents). Especially preferred is the use of a phenolic resin as a processing aid which is colorfast whereby such a phenolic resin has processing-technological advantages, for example, with respect to flowability and tackiness of the rubber mixture during tire building.
The vulcanization of the rubber composition requires sulfur or sulfur-producing substances (e.g., DTDM-dimorpholyldisulfide). However, it is also possible to initiate and perform vulcanization with the aid of other vulcanization agents (e.g., peroxide, resin, radiation). Furthermore, vulcanization-effecting substances such as accelerators or activators for the selected vulcanization type (e.g., for sulfur-induced vulcanization materials such as CBS: benzothiazyl-2-cyclohexylsulfenamide, TMTD: tetramethylthiuramdisulfide, TBBS: benzothiayl-2-tert.-butylsulfenamide) are to be added to the rubber mixture.
It is especially preferred when the non-black rubber mixture for sidewalls has an amount of aluminum powder of ≦1 phr, for example, 0.2 to 0.7 phr. It was surprisingly found that such amounts are sufficient in order to produce a metallic shine. Furthermore, an average particle size of the aluminum powder of <5·10
−5
m is preferred. The greater scattering effect of the smaller particles increases the shine of the vehicle tire sidewall.
The mica to be used for the inventive sidewall rubber mixture is an aluminum based silicate (e.g., biotite or muscovite) that is coated with a metal oxide, preferably titanium dioxide. It is preferred when the amount of metal oxide-coated mica is 8 to 20 phr. The combination of different individual particle size fractions can be used to optimize the reflective behavior of the sidewall of the pneumatic vehicle tire.
In addition, one or more other fillers can be added, for example, organic dyes and/or pigments which, however, do not have an effect on the reflective behavior and the metallic shine of the tire sidewall. Thus, reflective and colored, brilliantly shiny vehicle tire sidewalls can be produced.
The rubber components for the inventive sidewall composition is selected from, for example, ethylene propylene diene terpolymer, polyisoprene, styrene butadiene copolymer. Especially preferred is natural rubber, butyl rubber, halogenated butyl rubber, polybutadiene and/or an isobutylene polymer that is modified with p-bromometylstyrene.
With the inventive sidewall rubber mixture tire sidewalls are produced which, on the one hand, have excellent optical properties (reflectiveness and metallic shine) and, at the same time, still fulfill the mechanical/dynamic requirements with respect to wear resistance and resistance to ozone-in
Meier Heinrich
Teves Reinhard
Becker R W
Continental Aktiengesellschaft
Mulcahy Peter D.
R W Becker & Associates
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