Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
2001-04-10
2002-08-13
Michl, Paul R. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
active
06433066
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a silica-formulation based rubber composition designed to improve the processability and abrasion resistance.
2. Description of the Related Art
The technique of using aluminum-doped precipitated silica having a content of aluminum in the precipitated silica of 0.35 to 3 wt % by weight of silica as a reinforcing filler of a rubber composition for tire manufacture based on at least one type of diene-based polymer so as to improve the workability of a tire use diene-based rubber and reduce the amount of coupling agent used without causing deterioration of the properties of the composition is disclosed in Japanese Unexamined Patent Publication (Kokai) No. 8-277346, Japanese National Publication (Tokuhyo) No. 10-503748, and Japanese National Publication (Tokuhyo) No. 10-504012.
The precipitated silica generally being used as a reinforcing filler for rubber contains a slight amount of aluminum, but when the content of aluminum exceeds 0.24%, the inclusion in the rubber is poor and the Mooney viscosity becomes high, so the processability of the rubber composition formulated with this silica reinforcing filler is poor.
SUMMARY OF THE INVENTION
An object of the present invention is to achieve a reduction in the Mooney viscosity and an improvement in the abrasion resistance by blending a precipitated silica reduced in aluminum content into the rubber.
According to the present invention, there is provided a rubber composition containing precipitated silica having an aluminum content of 0.01 to 0.24 wt %. More preferably, there is provided a rubber composition containing precipitated silica having an aluminum content of 0.01 to 0.1 wt %.
Further, according to the present invention, there is provided a rubber composition containing precipitated silica having an aluminum content of 0.01 to 0.24 wt %, more preferably, 0.01 to 0.1 wt %, and having a CTAB specific area of 130 to 210 m
2
/g and a BET/CTAB ratio of 1.3 to 2.0
Further, according to the present invention, there is provided a rubber composition having, as a rubber ingredient, natural rubber, a diene-based synthetic rubber, or a mixture of these rubbers and having, in addition to the precipitated silica, carbon black in an amount of at least 10 parts by weight with respect to 100 parts by weight of the rubber ingredient.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
According to the present invention, it was discovered that, as the content of aluminum in the precipitated silica used as the reinforcing filler of the rubber composition is reduced, when the content falls below a certain amount, the inclusion of the silica in the rubber is improved and the Mooney viscosity falls, that is, the processability of the rubber composition is improved, and the abrasion resistance is improved.
According to the above discovery of the present invention, good results are obtained when the content of the aluminum in the precipitated silica is from 0.01 to 0.24 wt %. If the content of the aluminum is more than 0.24 wt %, the inclusion of the silica in the rubber becomes poor and the Mooney viscosity rises. Further, if the content of the aluminum is made 0.01 to 0.1 wt %, even better results are obtained in the above properties.
Further, the precipitated silica of the present invention, to secure reinforcement of the rubber, is preferably selected from ones having a CTAB specific area of the silica of 130 to 210 m
2
/g and a BET/CTAB ratio of 1.3 to 2.0. If the CTAB specific area is less than 130 m
2
/g and the BET/CTAB ratio is less than 1.3, securing the reinforcement becomes difficult. Further, if the CTAB specific area is over 210 m
2
/g and the BET/CTAB ratio is over 2.0, the preparation of the precipitated silica itself becomes difficult, the cost is increased, and the dispersion becomes poor.
The rubber ingredient used in the rubber composition of the present invention may be selected from natural rubber (NR) and a diene-based synthetic rubber such as polyisoprene rubber (IR), various types of styrene-butadiene copolymer rubbers (SBR), various types of polybutadiene rubbers (BR), an acrylonitrile-butadiene copolymer rubber (NBR), butyl rubber (IIR), etc. These may be used alone or in mixtures of two or more types. When using a mixture of two or more types of natural rubber and diene-based synthetic rubbers, a rubber mixture containing at least 60 parts by weight of natural rubber is preferable in terms of the object of the present invention.
The rubber composition of the present invention may further contain, in addition to the precipitated silica of the present invention, a usual carbon black in order to improve the electrical conductivity and abrasion resistance. This is added in an amount of at least 10 parts by weight, preferably 10 to 80 parts by weight, with respect to 100 parts by weight of the rubber ingredient. If the amount of the carbon black added is under 10 wt %, the effects are low, while if over 80 wt %, there is a problem of deterioration in the heat build-up of the rubber composition, and thus the proper ability of the silica can hardly be brought out.
The rubber composition of the present invention may further contain a silane coupling agent as desired. As the silane coupling agent, any silane coupling agent used for rubber compositions in the past may be used in the ordinary amounts of use.
The rubber composition of the present invention may contain, in addition to the above ingredients, a vulcanization or cross-linking agent, vulcanization or cross-linking accelerator, various types of oils, an antiaging agent, a plasticizer, and various other types of compounding agents used for tires and other general rubber products. The formulation may be kneaded and vulcanized to make a rubber composition by a general method and used for vulcanization or cross-linking. The amounts of the additives used may be made general amounts as in the past so far as not running counter to the object of the present invention.
Below, the present invention will be explained further with reference to examples and comparative examples, but the technical scope of the present invention is of course not limited to these examples.
Preparation of Test Samples
Using the precipitated silica of the types shown in the following Table 2, the ingredients of each of the rubber formulations shown in the following Table 1 other than the vulcanization accelerator and the sulfur were kneaded by a 1.8 liter closed mixer for 3 to 5 minutes and discharged when reaching 165±5° C. The vulcanization agent and sulfur were then added to this master batch and the mixture kneaded by an 8-inch open roll to obtain a rubber composition. The Mooney viscosity of the obtained rubber composition was measured.
Next, the composition was vulcanized by pressing in a 15×15×0.2 cm mold at 160° C. for 20 minutes to prepare the desired test piece (rubber sheet). This was used for measurement and evaluation of the dispersion, abrasion resistance, and tan &dgr; (60° C.).
TABLE 1
Rubber Formulation
Formula-
Formula-
Formula-
Formula-
tion 1
tion 2
tion 3
tion 4
Natural rubber 1)
100
60
50
Oil extended SBR 2)
137.5
SBR 3)
40
50
Silica
50
80
20
20
Carbon black 4)
30
30
Silane coupling
5
8
5
5
agent 5)
Zinc white 6)
5
3
3
3
Stearic acid 7)
3
1
1
1
Vulcanization
1
1
1
1
accelerator 8)
Sulfur 9)
2
2
2
2
Notes:
1) RSS#3
2) 37.5% oil extended emulsion polymerized styrene/butadiene rubber, SBR 1712 (made by Nippon Zeon)
3) Nipol 1502 (made by Nippon Zeon)
4) N339 (made by Showa Cabot)
5) Si 69 (made by Degussa)
6) Zinc white no. 3, industrial use zinc oxide
7) Stearic acid, industrial use stearic acid
8) Noccelar CZ (N-cyclohexyl-2-benzothiazylsulfenamide, made by Ouchi Shinko Chemical)
9) 5% oil extended powdered sulfur (made by Karuizawa Refineries)
TABLE 2
Type of Silica
A-1
A-2
A-3
A-4
A-5
A-6
Al content (wt %)
0.01
0.02
0.1
0.24
0.1
0.1
BET/CTAB
1.60
1.50
1.60
1.70
2.00
1.30
BET (m
2
/g)
240
222
235
253
260
274
CTAB (m
2
/g)
Kirino Yoshiaki
Yatsuyanagi Fumito
Arent Fox Kintner & Plotkin & Kahn, PLLC
Michl Paul R.
The Yokohama Rubber Co. Ltd.
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