Ru-containing polyoxotungstates and process for their...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C556S007000, C556S009000, C502S207000, C502S326000, C568S956000

Reexamination Certificate

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07858814

ABSTRACT:
The invention relates to polyoxometalates represented by the formula (An)m+[Ru2L2(XW11O39)2WO2]m−or solvates thereof, wherein A is a cation, n is the number of the cations, m is the charge of the polyanion, L is a ligand bound to ruthenium and is independently selected from group consisting of water, unsubstituted or substituted arenes, unsubstituted or substituted heteroarenes, unsaturated hydrocarbons, ethers, unsubstituted or substituted allyl, unsubstituted or substituted alkanes, nitriles, carboxylates, peroxides, peracids, phosphines, phosphanes, CO, OH−, peroxo, carbonate, NO3−, NO2−, NO−, NH3, amines, F−, Cl−, Br−, I−, SCN−, NCS−, NCO−and mixtures thereof and X is a heteroatom selected from Si, Ge, B and mixtures thereof, a process for their preparation and their use for the catalytic oxidation of organic molecules.

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