Route to glycals in the allal and gulal series

Details Route to glycals in the allal and gulal series Route to glycals in the allal and gulal series

1990-03-23

1992-04-14

Griffin, Ronald W.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536124, 536 41, 536 182, 549377, C07H 1102

Patent

active

051049821

ABSTRACT:
Axial anomeric sulfoxides generated via thiophenol Ferrier rearrangement of glucal and galactal derivatives are used to synthesize glycals of the gulal and allal series. An application of the method led to the synthesis of the esperamicin thiosugar.

REFERENCES:
patent: 4935503 (1990-06-01), Naicker et al.
Advances in Carbohydrate Chem & Biochem vol. 24, (1969) (Ferrier et al) pp. 199-266.

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