Roof sealant composition and method of applying

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Process of treating scrap or waste product containing solid...

Reexamination Certificate

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Reexamination Certificate

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06455598

ABSTRACT:

BACKGROUND OF THE INVENTION
This invention relates to a roof sealant composition, and more particularly, to a roof sealant which contains recycled paint sludge and a method for constructing a new or restoring an existing roof utilizing such a roof sealant.
Various types of materials are used for commercial and industrial roofing constructions. One common roofing construction is referred to as a builtup roof. Such a roof covering may comprise the application of a tar or asphalt base in multiple layers which are sometimes coated with loose gravel or aluminized reflective paint. Other common roof constructions include single-ply membrane roofs, which are generally comprised of EPDM, hypalon, or polyvinyl chloride. Another commonly used roof construction utilizes sheets of metal which are seamed together and adhered with sealant.
A present concern in the roofing industry is building roofs which will withstand a variety of weather conditions while providing long-lasting protection. For example, U.S. Pat. No. 4,016, 323 teaches a method of constructing a new roof system which utilizes a membrane comprising a fiberglass mesh having a rubberized asphalt adhesive on one side which adheres to the roof deck and a bituminous compound on the other side. Foam insulation is applied over the membrane followed by the application of a top layer of an elastomer.
Of further concern in the industry is extending the life of existing roof structures in order to avoid the expense of removing and replacing an entire roof. U.S. Pat. No. 4,241,107 teaches a method of coating an existing roof structure in which a cementitious coating is applied over a reinforcement of tar and felt paper covered with a wire mesh. A sealant comprising a rubberized or cement sealant is then applied over the cured coating.
However, the majority of sealant systems currently available are comprised of relatively expensive materials and the sealant compositions often contain solvents which leads to undesirably high volatile organic content (VOC) levels.
Accordingly, the need remains in the art for a method of treating a new or existing roof construction which utilizes cost-effective, environmentally friendly materials and which provides effective adhesion and sealing characteristics.
SUMMARY OF THE INVENTION
The present invention solves those needs by providing a roof sealant composition containing recycled paint sludge as a component and a method of treating a new or existing roof structure using such a sealant. The roof sealant is economic to produce, is environmentally friendly, provides excellent adhesion to various substrates, and exhibits good weathering characteristics.
According to one aspect of the present invention, a method is provided for treating a roof construction comprising the steps of applying a first coat of a roof sealant composition including recycled paint sludge onto the roof; applying a supportive mesh over the sealant; and applying a second coat of the roof sealant composition over the mesh. The method further includes the step of allowing the first coat of roof sealant to dry prior to applying the second coating, and allowing the second coat of the roof sealant composition to dry. Preferably, the mesh comprises a polyester mesh. Upon drying, a composite is formed which comprises the first and second dried roof sealant coating layers with the mesh layer inbetween. The composite exhibits elongation of greater than 300% and a tensile strength of greater than 500 psi.
The roof sealant composition preferably comprises from about 25 to 60% by weight recycled paint sludge and from about 30 to 50% by weight of an emulsion containing an elastomer. Preferably, the elastomer is a vinyl acetate-ethylene copolymer. The recycled paint sludge is preferably provided in the form of a water-based emulsion which preferably includes at least one non-ionic surfactant.
The roof sealant composition preferably further comprises from about 1 to 15% by weight fibers, preferably cellulose fibers, from about 0 to 5% by weight of a plasticizer, from about 0 to 1% by weight of a defoaming agent, from about 0 to 1% by weight of a microbiocide, from about 0 to 1% by weight of an antioxidant, from about 0 to 0.1% by weight of a UV light stabilizer, and from about 0 to 0.2% by weight of a UV light absorber.
The roof sealant composition (prior to application) preferably has a viscosity of from about 1000 cps to 3000 cps and a solids content of about 50 to 65% by weight. The roof sealant composition has a volatile organic content of less than 1 g/liter.
The roof sealant composition may be applied to a roof construction by rolling, brushing, troweling, or spraying. Upon drying, the roof sealant preferably exhibits elongation of between about 600 to 1200%, a tensile strength of greater than 50 psi, and a Shore A hardness of about 40.
Accordingly, it is an object of the present invention to provide an economical, environmentally friendly roof sealant composition and method for treating roofs which provides excellent adhesion and durability. This, and other objects and advantages of the present invention will become apparent to those skilled in the art from a reading of the following detailed description of the preferred embodiments and the appended claims.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
The roof sealant composition of the present invention exhibits excellent adhesion to a variety of roofing substrates including asphalt, asphalt shingles, galvanized steel, aluminum, painted surfaces, wood, masonry and brick. The roof sealant composition may be applied to a variety of roofing constructions including flat and low-slope roofs and other areas prone to leakage such as sealing seams, flashings, cracks, vents and skylights. The recycled paint sludge in the sealant composition provides several advantages over previously used sealant compositions in that it promotes good adhesion to a variety of substrates, it exhibits good weatherability, apparently due to the inherent presence of stabilizers in the paint sludge, and it is economical to use.
The recycled paint sludge may be prepared from paint sludge from the automotive industry, appliance industry, metal fabricating industry or other sources. The preferred method for making the paint sludge is described in U.S. Pat. No. 5,880,218, assigned to the same assignee as the present invention, the disclosure of which is hereby incorporated by reference. The paint sludge may essentially be produced by any method which is capable of removing water and/or solvent from raw paint sludge without curing the polymers in the paint sludge. After removal of water and/or solvent, the treated paint sludge is then preferably formed into an emulsion by combining the sludge with one or more non-ionic surfactants and water until a solids content of about 54-58% is achieved. Suitable non-ionic surfactants for use in the present invention include Tergitol XD, available from Union Carbide, and T-Det-N20, available from Harcros.
The recycled paint sludge emulsion is then formed into a roof sealant by combining it with the elastomeric latex emulsion, a defoamer, and a microbiocide. A preferred elastomeric emulsion is Airflex 526 BP, a vinyl acetate-ethylene copolymer water-based emulsion available from Air Products. Other suitable elastomers which may be used in the present invention include acrylic resins, neoprene, and nitrile rubbers.
Cellulose fibers are also preferably added to the mixture for purposes of providing rheological control. A stabilizing mixture is also preferably added to the emulsion which includes a plasticizer, antioxidant, a UV light stabilizer, and a UV light absorber. The resulting sealant composition has a Brookfield viscosity of about 1000 to 3000 cps, and a solids content of between about 50 and 60%. The final sealant composition is a homogeneous liquid which is blue-gray in appearance.
Prior to applying the roof sealant composition to a roof structure , the roof is preferably preconditioned as necessary by bridging any holes with fabric or mesh, treating rust, i.e., removing rust

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