Robust method for the preparation of high bromide tabular grain

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430567, G03C 1015, G03C 1035

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active

060430192

ABSTRACT:
A method is disclosed of manufacturing a radiation-sensitive tabular grain emulsion comprised of (a) providing in a stirred reaction vessel a host tabular grain emulsion containing greater than 50 mole percent bromide, based on silver, and a speed enhancing amount of iodide and (b) then introducing a silver salt solution into the stirred reaction vessel, wherein (1) the silver salt solution is introduced into the stirred reaction vessel at a rate sufficient to create a new grain population, (2) halting introduction of the silver salt solution for a time sufficient to allow the new grain population to be ripened out, and (3) repeating steps (1) and (2) from 3 to 20 times until silver introduced in steps (1) and (2) amounts to from 5 to 50 percent of total silver forming the radiation-sensitive tabular grain emulsion.

REFERENCES:
patent: 4433048 (1984-02-01), Solberg et al.
patent: 4434226 (1984-02-01), Wilgus et al.
patent: 4439520 (1984-03-01), Kofron et al.
patent: 5549879 (1996-08-01), Chow
patent: 5663041 (1997-09-01), Chang et al.
patent: 5667954 (1997-09-01), Irving et al.
Research Disclosure, vol. 382, Feb. 1996, Item 38213.

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