Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1993-10-14
1995-03-07
Zitomer, Fred
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526134, 526160, 526170, 526310, 526346, 5263471, 5263481, C08F 3204, C08F 464, C08G 6106
Patent
active
053959060
ABSTRACT:
The regiospecific (1,2-Me.sub.2 C.sub.5 H.sub.3).sub.2 ZrMe.sup.+ MeB(C.sub.6 F.sub.5).sub.3 - mediated ring-opening polymerization of methylenecyclobutane and its copolymerization with ethylene to polyolefins of microstructure --{CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.n and {--[CH.sub.2 CHR]--.sub.x [CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.y }.sub.n, respectively is disclosed.
REFERENCES:
R. Rossi et al. "On the Ring Opening Polymerization of Methylenecyclobutane", Macromolecules, 5(3), 247-9, 1972.
"Polymerisation du Methylenecyclobutane Obtention de L'Isocautchone," Pinazzi, P. et al., Die Makromolekulare Chemie, 147 (1971), pp. 15-33.
"Radical Polymerization of 3-Substituted-1-Methylenecyclobutanes," Hiraguri, Y. et al., Journal of Polymer Science: Part C: Polymer Letters, vol. 26, (1988), pp. 381-384.
"L'Isocautchone, Etude des parametres de cyclisation et d'Isomerisation": Pinazzi, et al., Die Makromolekulare Chemie, 148 (1971), pp. 81-92.
"Polymerization of Methylenecyclobutane, Synthesis of an Isopolyisoprene," Pinazzi, P. et al., Die Makromolekulare Chemie, 122 (1969), pp. 105-122.
"Vinylpolymerisation", Takemoto, K., et al., Die Makromolekulare Chemie, 109 (1967), pp. 81-86.
"On The Ring-Opening Polymerization of Methylenecyclobutane", Rosse, R. et al., vol. 5, No. 3, May-Jun. 1972, pp. 247-249.
Jia Li
Marks Tobin J.
Yang Xinmin
Northwestern University
Zitomer Fred
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