Ring-opening Ziegler olefin polymerization catalysts and polymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526134, 526160, 526170, 526310, 526346, 5263471, 5263481, C08F 3204, C08F 464, C08G 6106

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active

053959060

ABSTRACT:
The regiospecific (1,2-Me.sub.2 C.sub.5 H.sub.3).sub.2 ZrMe.sup.+ MeB(C.sub.6 F.sub.5).sub.3 - mediated ring-opening polymerization of methylenecyclobutane and its copolymerization with ethylene to polyolefins of microstructure --{CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.n and {--[CH.sub.2 CHR]--.sub.x [CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.y }.sub.n, respectively is disclosed.

REFERENCES:
R. Rossi et al. "On the Ring Opening Polymerization of Methylenecyclobutane", Macromolecules, 5(3), 247-9, 1972.
"Polymerisation du Methylenecyclobutane Obtention de L'Isocautchone," Pinazzi, P. et al., Die Makromolekulare Chemie, 147 (1971), pp. 15-33.
"Radical Polymerization of 3-Substituted-1-Methylenecyclobutanes," Hiraguri, Y. et al., Journal of Polymer Science: Part C: Polymer Letters, vol. 26, (1988), pp. 381-384.
"L'Isocautchone, Etude des parametres de cyclisation et d'Isomerisation": Pinazzi, et al., Die Makromolekulare Chemie, 148 (1971), pp. 81-92.
"Polymerization of Methylenecyclobutane, Synthesis of an Isopolyisoprene," Pinazzi, P. et al., Die Makromolekulare Chemie, 122 (1969), pp. 105-122.
"Vinylpolymerisation", Takemoto, K., et al., Die Makromolekulare Chemie, 109 (1967), pp. 81-86.
"On The Ring-Opening Polymerization of Methylenecyclobutane", Rosse, R. et al., vol. 5, No. 3, May-Jun. 1972, pp. 247-249.

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