Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate
Patent
1995-06-02
1998-03-24
Warzel, Mark L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From phenol, phenol ether, or inorganic phenolate
528128, 528397, 427422, 2641761, 264126, 264319, 2643282, 26433111, C08G 6110
Patent
active
057314004
ABSTRACT:
Rigid-rod and segmented rigid-rod polymers, methods for preparing the polymers and useful articles incorporating the polymers are provided. The polymers incorporate rigid-rod backbones with pendant solubilizing groups attached thereto for rendering the polymers soluble.
REFERENCES:
patent: 3431221 (1969-03-01), Hoess
patent: 3582498 (1971-06-01), Bilow et al.
patent: 3595811 (1971-07-01), Bilow
patent: 3677976 (1972-07-01), Miller et al.
patent: 3756982 (1973-09-01), Korshak
patent: 3826783 (1974-07-01), Bloch
patent: 3998864 (1976-12-01), Trevillyan
patent: 4108835 (1978-08-01), Arnold et al.
patent: 4108942 (1978-08-01), Chalk et al.
patent: 4207407 (1980-06-01), Helminiak et al.
patent: 4229566 (1980-10-01), Evers et al.
patent: 4263466 (1981-04-01), Colon et al.
patent: 4284834 (1981-08-01), Austin et al.
patent: 4326989 (1982-04-01), Colon et al.
patent: 4377546 (1983-03-01), Helminiak et al.
patent: 4384107 (1983-05-01), Rogers et al.
patent: 4393194 (1983-07-01), Guadiana et al.
patent: 4400499 (1983-08-01), Colon
patent: 4433132 (1984-02-01), Rogers et al.
patent: 4454307 (1984-06-01), Cheshire
patent: 4461886 (1984-07-01), Rogers et al.
patent: 4486576 (1984-12-01), Colon et al.
patent: 4503248 (1985-03-01), Guadiana et al.
patent: 4511623 (1985-04-01), Yoon et al.
patent: 4520189 (1985-05-01), Rogers et al.
patent: 4525413 (1985-06-01), Rogers et al.
patent: 4606875 (1986-08-01), Chenevey et al.
patent: 4608429 (1986-08-01), Rogers et al.
patent: 4614784 (1986-09-01), Kozakiewicz
patent: 4628125 (1986-12-01), Rogers et al.
patent: 4629777 (1986-12-01), Pfeifer
patent: 4857630 (1989-08-01), Kim
patent: 4977223 (1990-12-01), Arnold et al.
patent: 5102971 (1992-04-01), Himmler et al.
patent: 5151472 (1992-09-01), Valia
patent: 5169929 (1992-12-01), Tour et al.
Advanced Organic Chemistry (J. March), 2nd Edition, Published 1977, pp. 386-387.
Mezhikovskii et al., Chem. Abs., 78:98152j, 23 Apr. 1973.
English-language version of the article cited in 78:98152j, Mezhikovskii et al, "Thermal and Thermo-Oxidative Degradation of Polysulphophenylenequinones," Vysokomol. soyed. A14: No. 11, 2397-2404, 1972.
Trevillyan, Chem. Abs., 86:139404d, 9 May 1977.
Liogon'kii et al, Chem. Abs., 96:7293p, 4 Jan. 1982.
Matnishyan et al., "The Effect of Various Factors on the Synthesis of Polyarylenequinones," Vysokomol. soyed. A13: No. 5, 1009-1017, 1971.
Wallow et al,. "Synthesis of Soluble Rigid-Chain Polymers. An Ionic Poly (p-phenylene) Analog," Polymer Preprints, vol. 32, No. 3, 191-192, Aug. 1991.
Ballard et al, "Biotech Route to Polyphenylene," J. Chem. Soc., Chem. Commun., 954 (1983).
Ballauff, "Rigid Rod Polymers Having Flexible Side Chains. 1. Thermotropic Poly(1,4-phenylene 2,5-dialkoxyterephthalate)s," Makromol. Chem., Rapid Commun., vol. 7, pp. 407-414 (1986).
Beever et al. "Synthesis and Thermal Properties of Aromatic Polymers Containing 3,6-Quinoline Units in the Main Chain," Macromolecules, 12, 1033-1038 (1979).
Beever et al. "Polyquinolines: A Class of Rigid-Chain Polymers," J. Pol. Sci., Pol. Sym., 65, 41-53 (1978).
Braham et al, "Polyphenylenes vis Bis (2-pyrones) and Diethynylbenzenes. The Effect of m- and p-Phenylene Units in the Chain," Macromolecules, vol. 11, No. 2, 343, Mar.-Apr. 1978.
Chou et al, "Composites," Scientific American, Oct. 1986, pp. 193-202.
Colon et al, "Coupling of Aryl Chlorides by Nickel and Reducing Metals," J. Org. Chem., 51, 2627-2637 (1986).
Dicke et al, "Liquid Crystal Polymers. 14. Synthesis and Properties of Thermotropic Poly(1,4-Alkylphenylene Terephthalates)", Journal of Polymer Science, 21, 8, Aug. 1983, pp. 2581-2588.
Friedman et al, "Electron Impact and Thermal Fragmentation of Biphenylene," JACS, 90, 2321 (1968).
Gordon et al, "Thermally Stable Block Copolymers: A Potential Route to Molecular Composites," Polymer Preprints, American Chemical Society, Division of Polymer Chemistry, 27: 1, 311-312 (1986).
Harris et al, "Soluble Aromatic Polyimides from Phenylated Dianhydrides," J. Sci., Polym. Lett. Ed., 13, 1975, pp. 283-285.
Harris et al, "Synthesis and Characterization of Polyimides Based on 3,6-Diphenylpyromellitic Dianhydride," High Perf. Pol., 1, 3-16 (1989).
Hergenrother et al, "Phenyl-substituted Polyquinoxalines," Journal of Polymer Science: Part A-1, vol. 5, 1453-1466 (1967).
Hergenrother, "Polyphenlquinoxalines: Syntheisis, Characterization, and Mechanical Properties," Journal of Applied Polymer Science, vol. 18, pp. 1779-1791 (1974).
Hwang et al, "Composites on a Molecular Level: Phase Relationships, Processing, and Properties," J. Macromolecules Sci.-Phys., B22(2), 231-257 (1983).
Hwang et al, "Solution Processing and Properties of Molecular Composite Fibers and Films," Polymer Engineering and Science, Mid-Oct. 1983, vol. 23, No. 14, pp. 784-788.
Hwang et al, "Molecular Composites of Rigid Rod Poly-P-Phenylenebenzobisthiazole (PPBT) in Thermoplastic Matrices," Organic Coatings and Applied Poly Science Proceedings, vol. 48, pp. 929-933 (1983).
Jones et al, "Polymerization of Aromatic Nuclei. XXVI. Poly(p-phenylene): Friedel-Crafts Alkylation, Molecular Weight, and Propagation Mechanism," J. Polym. Sci., Polym. Chem. Ed., 19 89 (1981).
Krigbaum et al, "Nematogenic Polymers Having Rigid Chains. 1. Substituted Poly(p-Phenylene terephthalates)," Macromolecules, 18, 965-973 (1985).
LeBerre et al, "Electrochemical Polymerization of Para-dialkoxybenzenes. Part 1. Anodic Oxidation of Para-dimethoxybenzene in Dry Acetonitrile," J. Electroanal. chem., 218, 173 (1987).
Lenz, "Structure-Order Relationships in Liquid Crystalline Polyesters," Pure and Applied Chemistry, vol. 57, No. 11, pp. 1537-1544 (1985).
Lindow et al, "Pyrolysis of Biphenylene," JACS, 89, 1271 (1967).
Maruyama et al, "Preparation and Properties of Poly(methylpyridine-2,5-diyl)s," Chemistry Letters, 643-646 (1992).
Marvel et al, "Preparation and Aromatization of Poly-1,3-cyclohexadine," JACS, 81, 448 (1959).
Mukamal et al, "Diels-Alder Polymers. III. Polymers Containing Phenylated Phenylene Units," Journal of Polymer Science: Part A-1, vol. 5, 2721-2729 (1967).
Noll et al, "Poly(phenyl-1,4-phenylene), A Temperature-resistant, Soluble, and Melt-processable Derivative of Poly(p-phenylene)," Makromol. Chem., Rapid Commun. 11, 485-493 (1990).
Norris et al, "Synthesis and Solution Properties of Phenylated Polyquinolines," Macromolecules, 9, 496-505 (1976).
Reck et al, "Combined Liquid-Crystalline Polymers: Rigid Rod and Semi-Flexible Main Chain Polyesters with lateral Mesogenic Groups," Makromol. Chem., Rapid Commun., vol. 7, pp. 389-396 (1986).
Rehahn et al., "Soluble Poly(para-phenylene)s," 3.sup.a), Makromol. Chem. 191, 1991-2003 (1990).
Rehahn et al., "Soluble Poly(para-phenylene)s. 1. Extension of the Yamamoto Synthesis to Dibromobenzenes Substituted with Flexible Side Chains," Polymer (Jun. 1989), pp. 1054-1059.
Rehahn et al, "Soluble poly(para-phenylene)s. 2. Improved synthesis of poly(para-2,5-di-n-hexylphenylene) via Pd-catalyzed coupling of 4-bromo-2,5-di-n-hexylbenzeneboronic acid." Polymer, 30, 1060-1062 (1989).
Rehahn et al, "A High-Yield Route to 2,5-Di-n-alkyl-1,4-benzenedicarboxylic Acids," Synthesis, 386-388 (1988)
Reinhardt et al, "Pendant Oxy and Thioarylene Aromatic Heterocyclic Polymers," Polym. Prepr. (American Chemical Society, Division of Polymer Chemistry), 23 (2) , 119 (1982).
Rogers et al, "Highly Amorphous, Birefringent, Para-Linked Aromatic Polyamides," Macromolecules, 18, 1058-1068 (1985).
Satoh et al, "Properties of Highly Conducting Poly(p-Phenylene) Film Prepared by an Electrochemical Method," Polymer Communications, 26, 396 (1985).
Schilling et al, "Diels-Alder Polymerizations. VI. Phenylated Polypenylenes from Bis-2-pyrones and p-Diethynylbenzene," Macromolecules, vol. 2, No. 1, Jan.-Feb. 1969.
Stille et al, "Poly(p-Phenylene) ," Macromolecules, 4, 515 (1971).
Stille et al, "Polyquinolines," Macromolecules, 14, 870-880 (1981).
Stille et al, "Diels-Alder Polyers: Polyphenylenes Containing Alternating Phenylene and Triphenylphenylene Units," Journal of Polymer Science, Part B-7, 525 (1969).
Stille et al, "Polyquinolines Containing Fluorene and A
Gagne Robert R.
Marrocco III Matthew Louis
Trimmer Mark Steven
Wang Ying
Maxdem Incorporated
Warzel Mark L.
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