Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate
Patent
1995-01-05
1997-08-05
Warzel, Mark L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From phenol, phenol ether, or inorganic phenolate
528126, 528128, 528171, 528172, 528174, 528223, 528226, 528228, 528224, 528229, 528397, 525153, C08G 802, C08G 1400
Patent
active
056543921
ABSTRACT:
Rigid-rod and segmented rigid-rod polymers, methods for preparing the polymers and useful articles incorporating the polymers are provided. The polymers incorporate rigid-rod backbones with pendant solubilizing groups attached thereto for rendering the polymers soluble.
REFERENCES:
patent: 3431221 (1969-03-01), Hoess
patent: 3582498 (1971-06-01), Bilow et al.
patent: 3595811 (1971-07-01), Bilow
patent: 3677976 (1972-07-01), Miller et al.
patent: 3756982 (1973-09-01), Korshak et al.
patent: 3826783 (1974-07-01), Bloch
patent: 3998864 (1976-12-01), Trevillyan
patent: 4108835 (1978-08-01), Arnold et al.
patent: 4108942 (1978-08-01), Chalk et al.
patent: 4207407 (1980-06-01), Helminiak et al.
patent: 4229566 (1980-10-01), Evers et al.
patent: 4263466 (1981-04-01), Colon et al.
patent: 4284834 (1981-08-01), Austin et al.
patent: 4326989 (1982-04-01), Colon et al.
patent: 4377546 (1983-03-01), Helminiak et al.
patent: 4384107 (1983-05-01), Rogers et al.
patent: 4393194 (1983-07-01), Guadiana et al.
patent: 4400499 (1983-08-01), Colon
patent: 4433132 (1984-02-01), Rogers et al.
patent: 4454307 (1984-06-01), Cheshire
patent: 4461886 (1984-07-01), Rogers et al.
patent: 4486576 (1984-12-01), Colon et al.
patent: 4503248 (1985-03-01), Gaudiana et al.
patent: 4511623 (1985-04-01), Yoon et al.
patent: 4520189 (1985-05-01), Rogers et al.
patent: 4525413 (1985-06-01), Rogers et al.
patent: 4606875 (1986-08-01), Chenevey et al.
patent: 4608429 (1986-08-01), Rogers et al.
patent: 4614784 (1986-09-01), Kozakiewicz
patent: 4628125 (1986-12-01), Rogers et al.
patent: 4629777 (1986-12-01), Pfeifer
patent: 4857630 (1989-08-01), Kim
patent: 4977223 (1990-12-01), Arnold et al.
patent: 5102971 (1992-04-01), Himmler et al.
patent: 5151472 (1992-09-01), Valia
patent: 5169929 (1992-12-01), Tour et al.
Mezhikovskii et al., Chem. Abs., 78:98152j, 23 Apr. 1973.
English-language version of the article cited in 78:98152j, Mezhikovskii et al, "Thermal and Thermo-Oxidative Degradation of Polysulphophenylenequinones," Vysokomol. soyed. A14: No. 11, 2397-2404, 1972.
Trevillyan, Chem. Abs., 86:139404d, 9 May 1977.
Liogon'kii et al, Chem. Abs., 96:7293p, 4 Jan. 1982.
Matnishyan et al., "The Effect of Various Factors on the Synthesis of Polyarylenequinones," Vysokomol. soyed. A13: No. 5, 1009-1017, 1971.
Wallow et al., "Synthesis of Soluble Rigid-Chain Polymers. An Ionic Poly(p-phenylene) Analog," Polymer Preprints, vol. 32, No. 3, 191-192, Aug. 1991.
A. Noll et al, "Poly(phenyl-1,4-phenylene), A Temperature-resistant, Soluble, and Melt-processable Derivative of Poly(p-phenylene)," Makromol. Chem., Rapid Commun. 11, 485-493 (1990).
R. Matthias et al, "Soluble Poly(para-phenylene)s, 3.sup.a), " Makromol. Chem., 191, 1991-2003 (1990).
T. Maruyama et al, "Preparation and Properties of Poly-(methylpyridine-2,5-diyl)s," Chemistry Letters, 643-646 (1992).
Sutherlin et al, "Rigid-Rod Polyquinolines with Extended Aryl., Ether Pendent Groups: An Approach to Solubility Enhancement," Macromolecules 18, No. 12, 2669-2675 (1985).
Mukamal et al, "Diels-Alder Polymers. III. Polymers Containing Phenylated Pheylene Units," Journal of Polymer Science: Part A-1, vol. 5, 2721-2729 (1967).
Wolfe et al, "Rigid-Rod Polymers. 1. Synthesis and Thermal Properties of Para-Aromatic Polymers with 2,6-Benzobisoxazole Units in the Main Chain," Macromolecules, 14, 909-915 (1981).
Stille et al, "Diels-Alder Polymers: Polyphenylenes Containing Alternating Phenylene and Triphenylphenylene Units," J. Polym. Sci., Part B, 7, 525 (1969).
Dicke et al, "Liquid Crystal Polymers. 14. Synthesis and Properties of Thermotropic Poly(1,4-Alkylphenylene Terephthalates)," Journal of Polymer Science, 21, 8, Aug. 1983, pp. 2581-2588.
Braham et al, "Polyphenylenes vis Bis(2-pyrones) and Diethynylbenzenes. The Effect of m-and p-Phenylene Units in the Chain," Macromolecules, vol. 11, No. 2, 343, Mar.-Apr. 1978.
Chou et al, "Composites,"Scientific American, Oct. 1986, pp. 193-202.
Schilling et al, "Diels-Alders Polymerizations. VI. Phenylated Polyphenylenes from Bis-2-pyrones and p-Diethynylbenzene," Macromolecules, vol. 2, No. 1, Jan.-Feb. 1969.
Zhou et al, "Liquid Crystal Polymers. 15. Synthesis and Liquid Crystalline Properties of Alkyl-Substituted Polyesters," Journal of Polymer Science: Polymer Chemistry Edition, vol. 21, 3313-3320 (1983).
Lenz, R.W., "Structure-Order Relationships in Liquid Crystalline Polyesters," Pure and Applied Chemistry, vol. 57, No. 11, pp. 1537-1544 (1985).
Zhou et al, "Liquid Crystal Polymers. 17. Thermotropic Properties of Random Copolyesters of Monotropic and Enantiotropic Polymers," Canadian Journal of Chemistry, vol. 63, pp. 181-183, (1985).
Ballauff "Rigid Rod Polymers Having Flexible Side Chains. 1. Thermotropic Poly(1,4-phenylene2,5-dialkoxyterephthalate)s," Makromol. Chem., Rapid Commun., vol. 7, pp. 407-414 (1986).
Reck et al, "Combined Liquid-Crystalline Polymers: Rigid Rod and Semi-Flexible Main Chain Polyesters with Lateral Mesogenic Groups," Makromol. Chem., Rapid Commun., vol. 7, pp. 389-396 (1986).
Krigbaum et al, "Nematogenic Polymers Having Rigid Chains. 1. Substituted Poly(p-phenylene terephthalates)," Macromolecules, 18, 965-973 (1985).
Hwang et al, "Composites on a Molecular Level: Phase Relationships, Processing, and Properties," J. Macromolecules Sci.-Phys., B22(2), 231-257 (1983).
Hwang et al, "Solution Processing and Properties of Mulecular Composite Fibers and Films," Polymer Engineering and Science, Mid-Oct., 1983, vol. 23, No. 14, pp. 784-788.
Wellman et al, "Rodlike Polymer Reinforecment of an Amorphous Polymer Matrix AB-PBI/PBT," ACS Organic Cost. Plast. Chem., 93, 783 (1980).
Hwang et al, "Molecular Composites of Rigid Rod Poly-P-Phenylenebenzobis-thiazole (PPBT) in Thermoplastic Matrices," Organic Coatings and Applied Pol Science Proceeings, vol. 48, pp. 929-933 (1983).
Hergenrother et al, "Phenyl-Substituted Polyquinoxalines," Journal of Polymer Science: Part A-1, vol. 5, 1453-1466 (1967).
Wolfe et al, "Rigid-Rod Polymers. 2. Synthesis and Thermal Properties of Para-Aromatic Polymers with 2,6-Benzobisthiazole Units in the Main Chain," Macromolecules, 14, 915-920 (1981).
Hergenrother, P., "Polyphenylquinoxalines: Synthesis, Characterization, and Mechanical Properties," Journal of Applied Polymer Science, vol. 18, pp. 1779-1791 (1974).
Harris et al, "Soluble Aromatic Polyimides From Phenylated Dianhydrides," J. Sci., Polym. Lett. Ed., 13, 1975, pp. 283-285.
Reinhardt et al, "Pendant Oxy and Thioarylene Aromatic Heterocyclic Polymers Polym. Prepr.", (Am. Chem. Soc., Div. Polym. Chem.) 23 (2), 119 (1982).
Gordon et al, "Thermally Stable Block Copolymers: A Potential Route to Molecular Composites," Polymer Preprints, American Chemical Society, Division of Polymer Chemistry, 27: 1, 311-312 (1986).
Yamamoto et al, "A Novel Type of Polycodensation Utilizing Transition Metal-Catalyzed C--C Coupling. I. Preparation of Thermostable Polyphenylene Type Polymers," Bulletin of the Chemical Society, vol. 51, No. 7, Jul. 1978.
Lindow et al, "Pyrolysis of Biphenylene," JACS, 89, 1271 (1967).
Friedman et al, "Electron Impact and Thermal Fragmentation of Biphenylene," JACS, 90 2321 (1968).
Marvel et al, "Preparation and Aromatization of Poly-1,3-cyclohexadine," JACS, 81 448 (1959).
Stille et al, "Poly(p-phenylene)," Macromolecules, 4, 515 (1971).
Satoh et al, "Properties of Highly Conducting Poly(p-phenylene) Film Prepared by an Electrochemical Method," Polymer Communications, 26, 396 (1985).
Ballard et al, "Biotech Route to Polyphenylene," J. Chem. Soc., Chem Commun., 954 (1983).
Jones et al, "Polymerization of Aromatic Nuclei. XXVI. Poly(p-Phenylene): Friedel-Crafts Alkylation, Molecular Weight, and Propagation Mechanism," J. Polym. Sci., Polym. Chem. Ed., 19, 89 (1981).
LeBerre et al, "Electrochemical Polymerization of Paradialkoxybenzenes. Part 1. Anodic Oxidation of Paradimethoxybenzen in Dry Acetonitrile," J. Electroanal. Chem., 218, 173 (1987).
Kirk-Othmer, Encyclopaedia of Chemical Technology, 18, 704-719 (Polyimides).
Sales Brochure entitled "Polyphenylene Precursor PPPl," Imperial Chemical Industries PLC, Runcorn Che
Gagne Robert R.
Marrocco III Matthew Louis
Trimmer Mark Steven
Wang Ying
Maxdem Incorporated
Warzel Mark L.
LandOfFree
Rigid-rod polymers does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Rigid-rod polymers, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Rigid-rod polymers will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1075665