Rhodium-catalyzed olefin dimerization

Details Rhodium-catalyzed olefin dimerization Rhodium-catalyzed olefin dimerization

1990-09-11

1992-03-24

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

562590, 556 7, 556 14, 556136, 502155, 502161, 502162, 502169, 585510, 585511, 585531, C07C 6700, C07C 5500, C07F 1500

Patent

active

050990616

ABSTRACT:
A process is disclosed for preparing functionalized linear olefins by dimerizing terminal olefins in the presence of a cationic rhodium compound. Novel rhodium compounds useful in this process are also disclosed.

REFERENCES:
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patent: 4692548 (1987-09-01), Drent
patent: 4786623 (1988-11-01), Grenowillet et al.
patent: 4889949 (1989-12-01), Grenowillet et al.
T. Alderson et al., Journal of the American Chemical Society 87, No. 24, 5638 (1965).
M. Brookhart and D. Lincoln, Journal of the American Chemical Society 110, 8719 (1988).
W. Nugent and R. McKinney, Journal of Molecular Catalysts 29, 65 (1985).

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