Reversible, electrochemically-switched lariat ethers

Details Reversible, electrochemically-switched lariat ethers Reversible, electrochemically-switched lariat ethers

1985-05-22

1986-12-23

Andrews, R. L.

Chemistry: electrical and wave energy

Processes and products

C25C 100

Patent

active

046311190

ABSTRACT:
This invention relates to novel heteromacrocyclic compounds which have electrochemically reducible sidearms containing uncharged Lewis basic donor groups appropriately placed to interact with a macroring-bound cation and an electrochemical switching process utilizing same. Reduction of the sidearm's aromatic residue produces a radical anion species. The resulting ligand binds a cation more strongly than does the neutral species. These compounds are therefore of utility as electrochemically controlled cation binders.

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